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Merck
CN

03101

Ammonium iodide

puriss., ≥99%

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About This Item

Linear Formula:
NH4I
CAS Number:
Molecular Weight:
144.94
PubChem Substance ID:
eCl@ss:
38050607
UNSPSC Code:
12352302
EC Number:
234-717-7
MDL number:
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vapor pressure

1 mmHg ( 210.9 °C)

grade

puriss.

assay

≥99%

impurities

≤0.001% heavy metals (as Pb), ≤0.01% thiosulfate (S2O3)

ign. residue

≤0.1% (as SO4)

loss

≤1% loss on drying, 105 °C

pH

4.5-6.5 (20 °C, 5%)

anion traces

chloride, bromide (as Cl)-: ≤200 mg/kg, iodate (IO3-): ≤100 mg/kg, sulfate (SO42-): ≤100 mg/kg

cation traces

As: ≤5 mg/kg, Fe: ≤10 mg/kg

SMILES string

N.I

InChI

1S/HI.H3N/h1H;1H3

InChI key

UKFWSNCTAHXBQN-UHFFFAOYSA-N

General description

Thin films of ammonium iodide were studied by far IR spectra from −170°C to room temperature. Laser excited Raman spectra of polycrystalline NH4I was also recorded.

Application

Ammonium iodide (NH4I) may be used in the following studies:
  • Cyanation protocol of aryl boronic acids, boronates and borate salts. It has a dual role in the protocol to provide iodide and nitrogen atom of the cyano moiety.
  • Synthesis of vinyl methyl sulfones.
  • As iodine source in the iodination of aromatic compounds.


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pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

STOT RE 1 Oral

target_organs

Thyroid

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Xiaofang Gao et al.
Chemical communications (Cambridge, England), 51(1), 210-212 (2014-11-20)
A novel ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones is described. The process proceeded smoothly under metal-free conditions with high stereoselectivity and good functional group tolerance. The reaction mechanism was revealed
Low-Frequency Vibrations in Ammonium Iodide and Ammonium Bromide.
Durig JR and Antion DJ.
J. Chem. Phys. , 51(9), 3639-3647 (1969)
Simple and regioselective oxyiodination of aromatic compounds with ammonium iodide and Oxone.
Mohan KVVK, et al.
Tetrahedron Letters, 45(43), 8015-8018 (2004)



Global Trade Item Number

SKUGTIN
B8378-5G04061832534268
B8378-100G04061833648407