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Merck
CN

12304

Ammonium iron(II) sulfate hexahydrate

puriss., ≥99% (manganometric)

Synonym(s):

Ammonium ferrous sulfate hexahydrate, Ammonium iron(II) sulfate, Mohr’s salt

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About This Item

Linear Formula:
(NH4)2Fe(SO4)2 · 6H2O
CAS Number:
7783-85-9
Molecular Weight:
392.14
NACRES:
NA.55
PubChem Substance ID:
329749695
UNSPSC Code:
12352302
EC Number:
233-151-8
MDL number:
MFCD00150530
Assay:
≥99% (manganometric)
Form:
solid

Key Documents

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InChI key

MQLVWQSVRZVNIP-UHFFFAOYSA-L

InChI

1S/Fe.2H3N.2H2O4S.6H2O/c;;;2*1-5(2,3)4;;;;;;/h;2*1H3;2*(H2,1,2,3,4);6*1H2/q+2;;;;;;;;;;/p-2

SMILES string

N.N.O.O.O.O.O.O.[Fe++].OS([O-])(=O)=O.OS([O-])(=O)=O

grade

puriss.

assay

≥99% (manganometric)

form

solid

shelf life

Shelf life is limited

reaction suitability

reagent type: catalyst
core: iron

pH

3-5 (20 °C, 50 g/L)

mp

100 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg

cation traces

Ca: ≤200 mg/kg, Cu: ≤20 mg/kg, Fe3+: ≤500 mg/kg, K: ≤100 mg/kg, Mg: ≤200 mg/kg, Na: ≤100 mg/kg, Zn: ≤100 mg/kg

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Disclaimer

will be oxidized by air

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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The crystal structure of Tutton's salts. VI. Vanadium (II), iron (II) and cobalt (II) ammonium sulfate hexahydrates.
Montgomery H, et al.
Acta Crystallographica, 22(6), 775-780 (1967)
Gong Zhengjun et al.
Talanta, 66(4), 1012-1017 (2008-10-31)
A simple, accurate, sensitive and selective flow injection catalytic kinetic spectrophotometric method for rapid determination of trace amounts of selenium is proposed in this paper. The proposed method is based on the accelerating effect of Se(IV) on the reaction of
Mixed ligand complexes of iron (II) and (III) with cyanide and aromatic di-imines.
Schilt AA.
Journal of the American Chemical Society, 82(12), 3000-3005 (1960)
Yu-Jung Chang et al.
Nutrition (Burbank, Los Angeles County, Calif.), 21(4), 520-524 (2005-04-07)
This study examined whether iron accumulated in ferritin-producing recombinant microbes is bioavailable to rats with iron deficiency. Rats induced with iron deficiency were treated with iron preparations of ferrous ammonium sulfate, horse spleen ferritin, control yeast, and ferritin-producing recombinant yeast
Kazumasa Kumamoto et al.
Free radical research, 39(9), 987-993 (2005-08-10)
Identification of free radicals was performed for the reaction mixtures of autoxidized 1,2-dilinoleoylphosphatidylcholine (DLPC) with ferrous ions (or DLPC hydroperoxide with ferrous ions) and of DLPC with soybean lipoxygenase using electron spin resonance (ESR), high performance liquid chromatography (HPLC)--ESR and
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