205303
Lithium perchlorate trihydrate
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About This Item
Linear Formula:
LiClO4 · 3H2O
CAS Number:
Molecular Weight:
160.44
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
232-237-2
MDL number:
InChI key
JAWYRNYHJJDXHX-UHFFFAOYSA-M
InChI
1S/ClHO4.Li.3H2O/c2-1(3,4)5;;;;/h(H,2,3,4,5);;3*1H2/q;+1;;;/p-1
SMILES string
[Li+].[H]O[H].[H]O[H].[H]O[H].[O-]Cl(=O)(=O)=O
form
crystals and lumps
reaction suitability
reagent type: oxidant
concentration
21-22% (chlorine basis (silver nitrate titration))
density
1.841 g/mL at 25 °C (lit.)
Quality Level
General description
Crystal structure of lithium perchlorate trihydrate (LiClO4.3H2O) has been investigated by X-ray and neutron diffraction studies. It exhibits pyroelectric properties.
Application
Lithium perchlorate trihydrate may be used to modify the membrane morphology of poly[(vinylidene fluoride)-co-trifluoroethylene] membranes, by doping it with varying concentrations of LiClO4.3H2O. It may be used to compose the polymer nanocomposite electrolyte (PNCE) films.
When used as a co-catalyst, accelerates the Baylis-Hillman reaction, the coupling of α,β-unsaturated carbonyls with aldehydes.
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
易制爆化学品
危险化学品
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Neutron diffraction refinement of pyroelectric lithium perchlorate trihydrate.
Lundgren JO, et al.
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, 38(1), 15-20 (1982)
The structure of lithium perchlorate trihydrate Li(H2O)3ClO4-an X-ray and neutron diffraction study.
Sequeira A, et al.
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, 31(6), 1735-1739 (1975)
Jian-Yu Lu et al.
Polymers, 13(3) (2021-01-28)
Hydroquinone (HQ) is one of the major deleterious metabolites of benzene in the human body, which has been implicated to cause various human diseases. In order to fabricate a feasible sensor for the accurate detection of HQ, we attempted to
Effect of the microsctructure and lithium-ion content in poly [(vinylidene fluoride)-co-trifluoroethylene]/lithium perchlorate trihydrate composite membranes for battery applications.
Costa CM, et al.
Solid State Ionics, 217, 19-26 (2012)
Ionic conduction and relaxation processes in melt compounded poly(ethylene oxide)-lithium perchlorate trihydrate-montmorillonite nanocomposite electrolyte.
Choudhary S and Sengwa RJ.
Indian Journal of Engineering and Materials Sciences, 18(2), 147-156 (2011)
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