205567
Zinc fluoride
powder, 99%
Synonym(s):
Zinc difluoride
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Linear Formula:
ZnF2
CAS Number:
Molecular Weight:
103.39
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
232-001-9
MDL number:
Assay:
99%
Form:
powder
InChI key
BHHYHSUAOQUXJK-UHFFFAOYSA-L
InChI
1S/2FH.Zn/h2*1H;/q;;+2/p-2
SMILES string
F[Zn]F
vapor pressure
1 mmHg ( 970 °C)
assay
99%
form
powder
reaction suitability
reagent type: catalyst
core: zinc
mp
872 °C (lit.)
density
4.95 g/mL at 25 °C (lit.)
General description
Zinc fluoride is a Lewis acid catalyst that can be used in a variety of reactions including esterification, Mukaiyama aldol reaction, Mannich reaction, Friedel-Crafts alkylation, and allylation. It can also be used as an additive in numerous catalytic transformations.
Application
Zinc fluoride can be used as a catalyst to synthesize optically active β-amino ketones and esters via asymmetric Mannich reaction.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Irrit. 2
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
危险化学品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Zinc Fluoride
Turcotte-Savard M, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Novel sol-gel prepared zinc fluoride: synthesis, characterisation and acid-base sites analysis.
Guo Y, et al.
Journal of Materials Chemistry, 22(29), 14587-14593 (2009)
Theoretical studies of valence orbital binding energies in solid zinc sulfide, zinc oxide, and zinc fluoride.
Tossell JA.
Inorganic Chemistry, 16(11), 2944-2949 (1977)
Shinsuke Hayashi et al.
The Journal of chemical physics, 129(4), 044313-044313 (2008-08-07)
Highly correlated ab initio calculations have been performed for an accurate determination of the electronic structure and of the spectroscopy of the low lying electronic states of the ZnF system. Using effective core pseudopotentials and aug-cc-pVQZ basis sets for both
Shū Kobayashi et al.
Journal of the American Chemical Society, 124(20), 5640-5641 (2002-05-16)
The catalytic, diastereo- and enantioselective Mannich-type reaction of a hydrazono ester with silyl enol ethers in aqueous media has been successfully achieved with ZnF(2), a chiral diamine ligand, and trifluoromethanesulfonic acid.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service