205567
Zinc fluoride
powder, 99%
Synonym(s):
Zinc difluoride
Sign Into View Organizational & Contract Pricing
Select a Size
About This Item
Linear Formula:
ZnF2
CAS Number:
Molecular Weight:
103.39
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
Assay:
99%
Form:
powder
vapor pressure
1 mmHg ( 970 °C)
Assay
99%
form
powder
reaction suitability
reagent type: catalyst
core: zinc
mp
872 °C (lit.)
density
4.95 g/mL at 25 °C (lit.)
SMILES string
F[Zn]F
InChI
1S/2FH.Zn/h2*1H;/q;;+2/p-2
InChI key
BHHYHSUAOQUXJK-UHFFFAOYSA-L
Looking for similar products? Visit Product Comparison Guide
General description
Zinc fluoride is a Lewis acid catalyst that can be used in a variety of reactions including esterification, Mukaiyama aldol reaction, Mannich reaction, Friedel-Crafts alkylation, and allylation. It can also be used as an additive in numerous catalytic transformations.
Application
Zinc fluoride can be used as a catalyst to synthesize optically active β-amino ketones and esters via asymmetric Mannich reaction.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Irrit. 2
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
危险化学品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Zinc Fluoride
Turcotte-Savard M, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Theoretical studies of valence orbital binding energies in solid zinc sulfide, zinc oxide, and zinc fluoride.
Tossell JA.
Inorganic Chemistry, 16(11), 2944-2949 (1977)
Novel sol-gel prepared zinc fluoride: synthesis, characterisation and acid-base sites analysis.
Guo Y, et al.
Journal of Materials Chemistry, 22(29), 14587-14593 (2009)
J V Embleton et al.
Oral microbiology and immunology, 16(3), 182-184 (2001-05-19)
This study evaluated the ability of topically applied amine fluoride (AmF) and AmF-tin fluoride to inhibit the adhesion of Streptococcus sanguis within a parallel plate flow cell system. One of three AmF compounds and two tin fluoride preparations significantly reduced
Tomoaki Hamada et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(4), 1205-1215 (2005-11-04)
Catalytic asymmetric Mannich-type reactions of an alpha-hydrazono ester with silicon enolates in aqueous media have been developed by using ZnF2 and chiral diamines as catalysts. In these reactions, both Zn2+ and a fluoride anion were necessary to achieve high yields
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service