215112
Phosphorous acid
99%
Synonym(s):
Phosphonic acid
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About This Item
Linear Formula:
H3PO3
CAS Number:
Molecular Weight:
82.00
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352106
EC Number:
237-066-7
MDL number:
Assay:
99%
Form:
crystals or chunks, flakes
Quality Level
assay
99%
form
crystals or chunks, flakes
pH
(acidic)
solubility
water: soluble
density
1.651 g/mL at 25 °C (lit.)
SMILES string
[H]P(O)(O)=O
InChI
1S/H3O3P/c1-4(2)3/h4H,(H2,1,2,3)
InChI key
ABLZXFCXXLZCGV-UHFFFAOYSA-N
General description
Phosphorous acid (or phosphonic acid) is a phosphorus oxoacid commonly used as an intermediate in chemical synthesis for the production of various phosphorus compounds. It is also used as a strong reducing agent in organic synthesis.
Application
Phosphorous acid (H3PO3, orthophosphorous acid) may be used as one of the reaction components for the synthesis of the following:
- α-aminomethylphosphonic acids via Mannich-Type Multicomponent Reaction
- 1-aminoalkanephosphonic acids via amidoalkylation followed by hydrolysis
- N-protected α-aminophosphonic acids (phospho-isosteres of natural amino acids) via amidoalkylation reaction
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A
Storage Class
8A - Combustible corrosive hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
危险化学品
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Amidoalkylation of phosphorous acid.
Vinyukov AV, et al.
Russ. J. Gen. Chem., 85(2), 366-369 (2015)
L Qi et al.
Langmuir : the ACS journal of surfaces and colloids, 28(31), 11448-11456 (2012-07-17)
In a recent publication, we have highlighted the potential of phosphonic acid terminated PEG oligomers to functionalize strong UV absorption cerium oxide nanoparticles, which yield suspensions that are stable in aqueous or organic solvents and are redispersible in different solvents
Alain Graillot et al.
Journal of hazardous materials, 244-245, 507-515 (2012-11-28)
In order to remove metal ions from wastewaters, thermosensitive copolymers bearing sorption properties toward metal cations were prepared by free radical copolymerization between the N-n-propylacrylamide (NnPAAm) and the (dimethoxyphosphoryl)methyl 2-methylacrylate (MAPC1), followed by a hydrolysis of the phosphonated esters into
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 215112-500G | 04061837759970 |
| 215112-100G | 04061838773395 |
| 215112-2KG | 04061838773401 |
| 215112-4X2KG | 04061838773418 |