234125
Iron(III) ferrocyanide
Synonym(s):
Ferric ferrocyanide, Ferrihexacyanoferrate, Ferrocin, Prussian blue
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About This Item
Linear Formula:
Fe4[Fe(CN)6]3
CAS Number:
Molecular Weight:
859.23
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-875-5
MDL number:
Form:
powder
InChI key
DNMNDNSFJMUUFM-UHFFFAOYSA-N
InChI
1S/18CN.7Fe/c18*1-2;;;;;;;/q;;;;;;;;;;;;;;;;;;3*-4;4*+3
SMILES string
[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N
form
powder
concentration
≥30% (ICP)
λmax
694 nm
Quality Level
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Application
Iron(III) ferrocyanidecyclic can be used as:
- A catalyst to synthesize cyclic carbonates by reaction between carbon dioxide and epoxides.
- A precursor to prepare Fe-Fe3C nanoparticle encapsulated N-doped graphene layers via pyrolysis.
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Y Vaheb et al.
Journal of nanoscience and nanotechnology, 12(11), 8710-8714 (2013-02-21)
We investigate the assembly of Prussian blue and Cs-Co-Cr Prussian blue analogue molecular nanomagnets into nano-patterned electrodes. Pd or Au gaps - 7-50 nm were fabricated on a SiO2/Si substrate using standard electron beam lithography and lift-off. Nanomagnets were positioned
Lijuan Han et al.
Biosensors & bioelectronics, 43, 120-124 (2013-01-08)
In this study, we report a triple-component sensor fabricated by freestanding graphite felt (GF), platinum nanoparticles (Pt) and Prussian blue (PB). Pt is ultrasonically-electrodeposited on GF to increase the conductivity and to render the catalysts to the chemical deposition of
Prussian blue and its analogues: electrochemistry and analytical applications.
Karyakin AA.
Electroanalysis, 13(10), 813-819 (2001)
Vasanthi Siruguri et al.
The Indian journal of medical research, 136(1), 89-97 (2012-08-14)
The present study was carried out on stored rice variety PAU 201 in Punjab that was not permitted for milling and public distribution due to the presence of damaged grains at levels exceeding the regulatory limits of 4.75 per cent.
Electrochemistry of polynuclear transition metal cyanides: Prussian blue and its analogues.
Itaya K, et al.
Accounts of Chemical Research, 19(6), 162-168 (1986)
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