234125
Iron(III) ferrocyanide
Synonym(s):
Ferric ferrocyanide, Ferrihexacyanoferrate, Ferrocin, Prussian blue
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About This Item
Linear Formula:
Fe4[Fe(CN)6]3
CAS Number:
Molecular Weight:
859.23
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-875-5
MDL number:
Form:
powder
InChI key
DNMNDNSFJMUUFM-UHFFFAOYSA-N
InChI
1S/18CN.7Fe/c18*1-2;;;;;;;/q;;;;;;;;;;;;;;;;;;3*-4;4*+3
SMILES string
[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N
form
powder
concentration
≥30% (ICP)
λmax
694 nm
Quality Level
Related Categories
Application
Iron(III) ferrocyanidecyclic can be used as:
- A catalyst to synthesize cyclic carbonates by reaction between carbon dioxide and epoxides.
- A precursor to prepare Fe-Fe3C nanoparticle encapsulated N-doped graphene layers via pyrolysis.
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Lihua Jin et al.
Chemical communications (Cambridge, England), 49(3), 243-245 (2012-11-24)
A highly robust electrochemically controlled fluorescence switch based on ultrasmall Au nanoclusters has been designed by the aid of the electrochemical redox reaction of prussian blue.
Electrochemistry of polynuclear transition metal cyanides: Prussian blue and its analogues.
Itaya K, et al.
Accounts of Chemical Research, 19(6), 162-168 (1986)
Guanglei Fu et al.
Talanta, 97, 438-444 (2012-07-31)
A glucose biosensor was fabricated based on electrostatic self-assembly in combination with in situ photo-cross-linking of glucose oxidase (GOx) and diazoresin-chitosan (DAR-CS) on Prussian blue deposited multi-walled carbon nanotubes (PB-MWNTs) backbone. It was demonstrated that GOx was initially ionically deposited
The crystal structure of Prussian blue: Fe4 [Fe (CN)6]3. xH2O.
Buser HJ, et al.
Inorganic Chemistry, 16(11), 2704-2710 (1977)
Y Vaheb et al.
Journal of nanoscience and nanotechnology, 12(11), 8710-8714 (2013-02-21)
We investigate the assembly of Prussian blue and Cs-Co-Cr Prussian blue analogue molecular nanomagnets into nano-patterned electrodes. Pd or Au gaps - 7-50 nm were fabricated on a SiO2/Si substrate using standard electron beam lithography and lift-off. Nanomagnets were positioned
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