249866
Titanium(IV) chloride solution
1.0 M in methylene chloride
Synonym(s):
Titanium tetrachloride
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About This Item
Linear Formula:
TiCl4
CAS Number:
Molecular Weight:
189.68
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
Form:
liquid
Quality Level
vapor pressure
24.09 psi ( 55 °C), 6.93 psi ( 20 °C)
form
liquid
reaction suitability
reagent type: catalyst
core: titanium
concentration
0.95-1.10 M NaOH (titration), 1.0 M in methylene chloride
density
1.365 g/mL at 25 °C
SMILES string
Cl[Ti](Cl)(Cl)Cl
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
General description
Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.
Application
Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
supp_hazards
Storage Class
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
危险化学品
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Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Bratindranath Mukherjee et al.
Nanoscale, 5(1), 269-274 (2012-11-20)
The surface treatment of an anodized TiO(2) nanotube (T_NT) is very desirable for enhancing its photoelectrochemical properties and often is a prerequisite to deposition of any overlying layer for photoactivity efficiency improvement. This study provides a comparative analysis of the
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 249866-100ML | 04061825928760 |
| 249866-4X100ML | 04061825928777 |
| 249866-800ML | 04061825936680 |