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Merck
CN

255823

Sigma-Aldrich

Lithium carbonate

greener alternative

ACS reagent, ≥99.0%

Synonym(s):

Carbolithium, Carbonic acid lithium salt

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About This Item

Linear Formula:
Li2CO3
CAS Number:
Molecular Weight:
73.89
Beilstein:
3999191
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21
Assay:
≥99.0%
Grade:
ACS reagent
Form:
powder
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grade

ACS reagent

Quality Level

Assay

≥99.0%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
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impurities

≤0.01% insol. dil. HCl
≤0.2% S compounds

pH

9-11 (1 g/L)

mp

618 °C (lit.)

anion traces

chloride (Cl-): ≤0.005%
nitrate (NO3-): ≤5 ppm

cation traces

Ca: ≤0.01%
Fe: ≤0.002%
K: ≤0.01%
NH4+: ≤5 ppm
Na: ≤0.1%
heavy metals: ≤0.002% (by ICP-OES)

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SMILES string

[Li+].[Li+].[O-]C([O-])=O

InChI

1S/CH2O3.2Li/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

XGZVUEUWXADBQD-UHFFFAOYSA-L

Gene Information

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General description

We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. LITHIUM CARBONATE is essential for sustainable energy solutions, particularly in lithium-ion batteries. Its eco-friendly properties enhance battery performance and longevity, supporting the transition to cleaner energy technologies while reducing environmental impact. Click here for more information.

Application

Lithium carbonate is an inorganic compound and serves as the precursor for the synthesis of several lithium compounds including Li-ion battery materials. It is also used in the glass and ceramic industry.
Lithium carbonate is used
  • In the synthesis of monoclinic phase lithium zirconate by heating with a mixture of zirconia and potassium carbonate at high temperature.
  • As a lithium precursor to synthesize solid-base catalyst [Li4SiO4] by simple solid-state reaction with rice husks. Li4SiO4 is used for biodiesel production.
  • In the synthesis of high-purity lithium hydroxide monohydrate by membrane electrolysis process using lithium sulfate as electrolyte.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Towards homonuclear J solid-state NMR correlation experiments for half-integer quadrupolar nuclei: experimental and simulated 11B MAS spin-echo dephasing and calculated 2JBB coupling constants for lithium diborate.
Barrow NS, et al.
Physical Chemistry Chemical Physics, 13(13), 5778-5789 (2011)
Xiaoyue Tan et al.
Journal of the American Society of Nephrology : JASN, 17(12), 3382-3393 (2006-11-04)
Deficiency in vitamin D and its active metabolites is a pathologic feature of chronic kidney diseases. Despite that tubular epithelial cells are the major sites of active vitamin D synthesis, little is known about the role of vitamin D in
Vanadium modified LiFePO4 cathode for Li-ion batteries.
Hong J, et al
Electrochemical and Solid-State Letters, 12(2), A33-A38 (2009)
Hart WA, et al.
The Chemistry of Lithium, Sodium, Potassium, Rubidium, Cesium and Francium, 355-355 (1973)
K E Morrison et al.
The Lancet. Neurology, 12(4), 339-345 (2013-03-05)
Lithium has neuroprotective effects in cell and animal models of amyotrophic lateral sclerosis (ALS), and a small pilot study in patients with ALS showed a significant effect of lithium on survival. We aimed to assess whether lithium improves survival in

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