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Merck
CN

291048

Iodine monochloride solution

1.0 M in methylene chloride

Synonym(s):

Chloroiodide solution, Wijs solution

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About This Item

Linear Formula:
ICl
CAS Number:
7790-99-0
Molecular Weight:
162.36
UNSPSC Code:
12352300
NACRES:
NA.55
PubChem Substance ID:
329753313
MDL number:
MFCD00011354
Beilstein/REAXYS Number:
3587194
Form:
liquid

Key Documents

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Product Name

Iodine monochloride solution, 1.0 M in methylene chloride

InChI

1S/ClI/c1-2

SMILES string

ClI

InChI key

QZRGKCOWNLSUDK-UHFFFAOYSA-N

form

liquid

concentration

0.95-1.10 M (by Na2S2O3, titration)
1.0 M in methylene chloride

density

1.42 g/mL at 25 °C

Quality Level

100

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Related Categories

signalword

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCW7458
MKCT6921
MKCR6709
MKCN5949
SHBL4604

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Polymethylbenzene complexes of iodine and iodine monochloride.
Andrews LJ and Keefer RM.
Journal of the American Chemical Society, 74(18), 4500-4503 (1952)
Ultrasonic-assisted synthesis of flavones by oxidative cyclization of 2'-hydroxychalcones using iodine monochloride.
Lahyani A and Trabelsi M.
Ultrasonics Sonochemistry, 31, 626-630 (2016)
Ahmed Khalil et al.
Nucleosides, nucleotides & nucleic acids, 33(12), 786-799 (2014-11-06)
The reaction of thymidine, 3-mono-, and 3,3',5'-trialkylsubstitued thymidine analogues with iodine monochloride (ICl) was investigated. Treatment with ICl resulted in rapid deglycosylation, anomerization, and isomerization of thymidine and 3-substituted thymidine analogues under various reaction conditions leading to the formation of
Cation radicals as intermediates in aromatic halogenation with iodine monochloride: solvent and salt effects on the competition between chlorination and iodination.
Hubig SM, et al.
The Journal of Organic Chemistry, 59(21), 6233-6244 (1994)
R M Passos et al.
Brazilian journal of medical and biological research = Revista brasileira de pesquisas medicas e biologicas, 24(8), 787-790 (1991-01-01)
Samples of Schistosoma mansoni soluble adult worm proteins (SWAP) were iodinated with 4-15 mumol I/mg protein using iodine monochloride. The capacity to elicit immediate hypersensitivity reactions of the iodinated derivatives was compared to that of the native SWAP preparations. The
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