291048
Iodine monochloride solution
1.0 M in methylene chloride
Synonym(s):
Chloroiodide solution, Wijs solution
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About This Item
Linear Formula:
ICl
CAS Number:
Molecular Weight:
162.36
UNSPSC Code:
12352300
NACRES:
NA.55
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587194
Form:
liquid
InChI
1S/ClI/c1-2
SMILES string
ClI
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
form
liquid
concentration
0.95-1.10 M (by Na2S2O3, titration), 1.0 M in methylene chloride
density
1.42 g/mL at 25 °C
Quality Level
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Related Categories
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
Storage Class
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
危险化学品
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Polymethylbenzene complexes of iodine and iodine monochloride.
Andrews LJ and Keefer RM.
Journal of the American Chemical Society, 74(18), 4500-4503 (1952)
Ultrasonic-assisted synthesis of flavones by oxidative cyclization of 2'-hydroxychalcones using iodine monochloride.
Lahyani A and Trabelsi M.
Ultrasonics Sonochemistry, 31, 626-630 (2016)
Cation radicals as intermediates in aromatic halogenation with iodine monochloride: solvent and salt effects on the competition between chlorination and iodination.
Hubig SM, et al.
The Journal of Organic Chemistry, 59(21), 6233-6244 (1994)
Ahmed Khalil et al.
Nucleosides, nucleotides & nucleic acids, 33(12), 786-799 (2014-11-06)
The reaction of thymidine, 3-mono-, and 3,3',5'-trialkylsubstitued thymidine analogues with iodine monochloride (ICl) was investigated. Treatment with ICl resulted in rapid deglycosylation, anomerization, and isomerization of thymidine and 3-substituted thymidine analogues under various reaction conditions leading to the formation of
K R Siebenlist et al.
Biochemistry, 39(46), 14171-14175 (2000-11-23)
There are conflicting ideas regarding the location of the carboxyl-terminal regions of cross-linked gamma-chain dimers in double-stranded fibrin fibrils. Some investigators believe that the chains are always oriented longitudinally along each fibril strand and traverse the contacting ends of abutting
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