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Merck
CN

311375

Antimony(III) chloride

ACS reagent, ≥99.0%

Synonym(s):

Antimony trichloride

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About This Item

Linear Formula:
SbCl3
CAS Number:
Molecular Weight:
228.12
PubChem Substance ID:
eCl@ss:
38080204
UNSPSC Code:
12352302
NACRES:
NB.24
EC Number:
233-047-2
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Form:
powder, crystals or chunks
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grade

ACS reagent

Quality Level

vapor density

7.9 (vs air)

vapor pressure

1 mmHg ( 49 °C)

assay

≥99.0%

form

powder, crystals or chunks

reaction suitability

reagent type: catalyst
core: antimony

impurities

≤0.05% insol. CHCl3

mp

73.4 °C (lit.)

anion traces

sulfate (SO42-): ≤0.005%

cation traces

As: ≤0.02%, Ca: ≤0.005%, Cu: ≤0.001%, Fe: ≤0.002%, K: ≤0.01%, Na: ≤0.02%, Pb: ≤0.005%

SMILES string

Cl[Sb](Cl)Cl

InChI

1S/3ClH.Sb/h3*1H;/q;;;+3/p-3

InChI key

FAPDDOBMIUGHIN-UHFFFAOYSA-K

Application

Antimony(III) chloride (SbCl3) is a Lewis acid catalyst that is used in various organic reactions such as polymerization, Friedel-Crafts acylations, reductions with NaBH4, ring opening of epoxides, cleavage of trityl ethers, Biginelli and chlorination reactions. It is also used as a precursor to synthesize other antimony salts.


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pictograms

CorrosionEnvironment

signalword

Danger

hcodes

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品

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Antimony (III) chloride-catalyzed ring opening of epoxides with anilines.
Singh MC and Peddinti RK.
Tetrahedron Letters, 48(41), 7354-7357 (2007)
Synthesis, structural characterization and cytotoxicity of the antimony (III) chloride complex with N, N-dicyclohexyldithiooxamide.
Ozturk II, et al.
Polyhedron, 52, 1403-1410 (2013)
Antimony (III) chloride-catalysed Biginelli reaction: a versatile method for the synthesis of dihydropyrimidinones through a different reaction mechanism
Cepanec I, et al.
Tetrahedron, 63(48), 11822-11827 (2007)



Global Trade Item Number

SKUGTIN
311375-100G04061826681466
311375-5G04061826681473