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Merck
CN

31235

Iron(III) sulfate hydrate

puriss. p.a., 21-23% Fe basis

Synonym(s):

Ferric sulfate hydrate

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About This Item

Linear Formula:
Fe2(SO4)3 · xH2O
CAS Number:
Molecular Weight:
399.88 (anhydrous basis)
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
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grade

puriss. p.a.

form

solid

concentration

21-23% Fe

impurities

≤0.01% insoluble in HCl

anion traces

chloride (Cl-): ≤50 mg/kg, nitrate (NO3-): ≤200 mg/kg, phosphate (PO43-): ≤30 mg/kg

cation traces

As: ≤5 mg/kg, Ca: ≤100 mg/kg, Cu: ≤20 mg/kg, Fe2+: ≤200 mg/kg, K: ≤100 mg/kg, Mg: ≤100 mg/kg, Na: ≤100 mg/kg, Zn: ≤50 mg/kg

SMILES string

[Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/2Fe.3H2O4S/c;;3*1-5(2,3)4/h;;3*(H2,1,2,3,4)/q2*+3;;;/p-6

InChI key

RUTXIHLAWFEWGM-UHFFFAOYSA-H

General description

Iron(III) sulfate hydrate, an iron (III) sulfate n-hydrate, is an Fenton-type salt.

Application

Iron(III) sulfate hydrate (Ferric sulfate hydrate) may be employed as catalyst for the reaction of perbenzyl glucal with various alcohols, via Ferrier rearrangement to afford 2,3-unsaturated D-O-glucosides.


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2

flash_point_f

Not applicable

flash_point_c

Not applicable

Storage Class

8A - Combustible corrosive hazardous materials

Regulatory Information

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Ferric sulfate hydrate-catalyzed O-glycosylation using glycals with or without microwave irradiation.
Zhang G, et al.
Tetrahedron, 64(2), 339344-339344 (2008)
Carmen Stavarache et al.
Ultrasonics sonochemistry, 9(6), 291-296 (2002-10-31)
The influence of ultrasounds (200 kHz frequency) on the decomposition of chlorobenzene (CB) in a water solution (around 100 ppm concentration) containing iron or palladium sulfates was investigated. The intermediates of the sonolysis were identified, thus allowing a deeper insight
Gal Frenkel et al.
The Journal of clinical pediatric dentistry, 37(2), 137-141 (2012-01-01)
To compare the long-term clinical and radiographic outcomes of pulpotomies in primary molars performed with white or gray Mineral Trioxide Aggregate (MTA) in combination with ferric sulfate (FS), when one package of MTA is used for multiple treatments. Sixty eight