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Merck
CN

31483

Nickel(II) sulfate hexahydrate

puriss. p.a., ACS reagent, 99-102.0%

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About This Item

Linear Formula:
NiSO4 · 6H2O
CAS Number:
Molecular Weight:
262.85
UNSPSC Code:
12352302
PubChem Substance ID:
EC Number:
232-104-9
MDL number:
Assay:
99-102.0%
Form:
crystals
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InChI key

RRIWRJBSCGCBID-UHFFFAOYSA-L

InChI

1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2

SMILES string

O.O.O.O.O.O.[Ni++].[O-]S([O-])(=O)=O

grade

ACS reagent, puriss. p.a.

vapor density

2.07 (vs air)

assay

99-102.0%

form

crystals

impurities

≤0.001% total nitrogen (N), ≤0.005% in water insoluble matters

pH

4-6 (20 °C, 5%)

anion traces

chloride (Cl-): ≤10 mg/kg

cation traces

Ca: ≤50 mg/kg, Co: ≤20 mg/kg, Cu: ≤20 mg/kg, Fe: ≤10 mg/kg, K: ≤50 mg/kg, Mg: ≤50 mg/kg, Mn: ≤5 mg/kg, Na: ≤100 mg/kg, Pb: ≤10 mg/kg, Zn: ≤20 mg/kg

suitability

complies for identity (IR)

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General description

Nickel(II) sulfate hexahydrate is a hydrated nickel salt. Its thermal decomposition in the presence of air and helium has been studied. Its crystals exist in monoclinic and tetragonal polymorphic forms.

Application

Nickel(II) sulfate hexahydrate may be used in the preparation of NiFe2O4 nanoparticles (NPs), which are required for the fabrication of a glucose biosensor.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

target_organs

Respiratory Tract

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Lan Chen et al.
International journal of molecular sciences, 22(5) (2021-03-07)
Nickel (Ni2+) is one of the most common allergens, affecting around 10-15% of the general population. As the demand for orthopedic implant surgery rises, the number of surgical revisions due to joint implant failure also increases. There is evidence that
Amperometric glucose biosensor based on NiFe2O4 nanoparticles and chitosan.
Luo L, et al.
Sensors and Actuators B, Chemical, 145(!), 293-298 (2010)
Mechanism and kinetics of thermal decomposition of nickel (II) sulfate (VI) hexahydrate.
Tomaszewicz E and Kotfica M.
Journal of Thermal Analysis and Calorimetry, 77(1), 25-31 (2004)
Polymorphism of nickel sulfate hexahydrate.
Angel RJ and Finger LW.
Acta Crystallographica Section C, Crystal Structure Communications, 44(11), 1869-1873 (1988)
Hsiao-Chi Chuang et al.
Toxicology and applied pharmacology, 266(2), 298-306 (2012-11-21)
Heart rate variability (HRV) has been reported to be a putative marker of cardiac autonomic imbalance caused by exposure to ambient particulate matter (PM). Our objective in this study was to determine the effects on HRV from exposure to nickel

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