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About This Item
Linear Formula:
MgO
CAS Number:
Molecular Weight:
40.30
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352303
EC Number:
215-171-9
MDL number:
Assay:
≥99% trace metals basis
Form:
powder
Product Name
Magnesium oxide, ≥99% trace metals basis, -325 mesh
InChI key
CPLXHLVBOLITMK-UHFFFAOYSA-N
InChI
1S/Mg.O
SMILES string
O=[Mg]
assay
≥99% trace metals basis
form
powder
reaction suitability
reagent type: catalyst
core: magnesium
loss
10% loss on ignition, 1000°C (absorbed H2O and CO2)
particle size
-325 mesh
mp
2852 °C (lit.)
Quality Level
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Analysis Note
Purity based on metallic impurity content.
Application
Magnesium oxide can be used as a catalyst in the:
- Dehydrogenation of n-octane to synthesize octenes.
- Solvent-free Knoevenagel condensation of aromatic aldehydes and ethyl cyanoacetate to synthesize electrophilic olefins.
General description
Magnesium oxide is a mild basic reagent used in acylations, alkylations, oxidations, reductions, formation of heterocycles, ring-opening of tertiary amines, nitration of aromatic acetals, hydrohalogenation, dehydrohalogenation, carbonylation of organomercurials, and serves as a leaving group to form alkenes.
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Effect of different catalyst supports on the (n, m) selective growth of single-walled carbon nanotube from Co-Mo catalyst.
Wang B, et al.
J. Mater. Sci., 44(12), 3285-3295 (2009)
Eagleson M.
Concise Encyclopedia Chemistry, 495-495 (1994)
Magnesium oxide-catalysed reaction of carbon dioxide with an epoxide with retention of stereochemistry.
Yano T, et al.
Chemical Communications (Cambridge, England), 12, 1129-1130 (1997)
Synthesis of ethylene and ethane by partial oxidation of methane over lithium-doped magnesium oxide.
Ito T and Lunsford JH.
Nature, 721-722 (1985)
Sanket A Deshmukh et al.
Physical chemistry chemical physics : PCCP, 14(44), 15593-15605 (2012-10-19)
Atomic scale characterization of the structure and dynamics of confined water molecules located near the metal oxide-aqueous interface is carried out using molecular dynamics simulations. Proximity effects on water molecules (H(2)O) near a magnesium oxide surface (MgO(100)) at room temperature
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