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Merck
CN

345695

Titanium(IV) chloride solution

1.0 M in toluene

Synonym(s):

Titanium tetrachloride

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About This Item

Linear Formula:
TiCl4
CAS Number:
7550-45-0
Molecular Weight:
189.68
NACRES:
NA.55
PubChem Substance ID:
329755036
UNSPSC Code:
12352300
MDL number:
MFCD00011267

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InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

form

liquid

reaction suitability

reagent type: catalyst
core: titanium

concentration

0.95-1.10 M NaOH (titration), 1.0 M in toluene

density

0.964 g/mL at 25 °C

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General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.

Application

TiCl4 can be used as a precursor for the synthesis of nanosized titaniuim dioxide.

signalword

Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH014

Storage Class

3 - Flammable liquids

flash_point_f

46.4 °F - closed cup

flash_point_c

8 °C - closed cup

Hazard Classifications

Acute Tox. 2 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBN6714
SHBN3587
SHBH9459
SHBB9156V
74997LJV

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Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Charles Dylan Turner et al.
Organic letters, 14(18), 4970-4973 (2012-09-08)
The Ti(IV)-catalyzed Ugi condensation of α-amino acids with electron-rich aromatic aldehydes performs adequately even with sterically demanding α-amino carboxylate salts. The reaction occurs diastereoselectively, in some cases with virtually complete diastereoselectivity. A stereochemical rationale for the reaction is proposed.
Kun Wang et al.
The oncologist, 20(3), 263-269 (2015-02-07)
The TERT promoter and FGFR3 gene mutations are two of the most common genetic events in urothelial bladder cancer (UBC), and these mutation assays in patient urine have been shown to be promising biomarkers for UBC diagnosis and surveillance. These
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