402990
一氯化碘
ACS reagent, 1.10±0.1 I/Cl ratio basis
别名:
氯化碘
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关于此项目
线性分子式:
ICl
化学文摘社编号:
分子量:
162.36
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
232-236-7
MDL number:
Grade:
ACS reagent
Form:
solid or liquid
Solubility:
acetic acid: soluble(lit.), acetone: soluble(lit.), alcohol: soluble(lit.), carbon disulfide: soluble(lit.)
grade
ACS reagent
Quality Segment
form
solid or liquid
impurities
≤0.005% insolubles
bp
97.4 °C (lit.)
solubility
acetic acid: soluble(lit.), acetone: soluble(lit.), alcohol: soluble(lit.), carbon disulfide: soluble(lit.)
density
3.24 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
ClI
InChI
1S/ClI/c1-2
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
General description
Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated. It affords electrically conducting solution on dissolution in polar solvents. Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.
Application
Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes. It may be used for the synthesis of flavones.
Iodine monochloride may be used in the synthesis of the following:
- 2-(4-haloisoquinolin-1-yl)ethanol derivatives
- 5-iodosalicylaldehydes
- 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines
- (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol
- (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable