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Merck
CN

515809

Ammonium sulfide solution

40-48 wt. % in H2O

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About This Item

Linear Formula:
(NH4)2S
CAS Number:
Molecular Weight:
68.14
UNSPSC Code:
12352300
eCl@ss:
38030205
PubChem Substance ID:
NACRES:
NA.21
MDL number:
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Quality Level

concentration

40-48 wt. % in H2O, 40.0-48.0% (titration by Na2S2O3)

refractive index

n20/D 1.467

bp

40 °C

density

1 g/mL at 25 °C

SMILES string

N.N.S

InChI

1S/2H3N.H2S/h2*1H3;1H2

InChI key

UXXGWUQNRMPNKH-UHFFFAOYSA-N

General description

Ammonium sulfide solution (aqueous ammonium sulfide) is a 40-48wt.% solution in water. Ammonium sulfide is an inorganic salt with a sulfurous odor, which is commonly used in the food industry as a flavoring agent. The influence of ammonium sulfide treatment on (100)GaAs (gallium arsenide) surfaces has been studied by x-ray photoelectron spectroscopy (XPS) and reflection high-energy electron diffraction (RHEED). Its potential as an alternative to hydrogen sulfide for the transformation of activated amides to thioamides by thiolysis has been investigated. The reaction of ammonium sulfide with 3-hydroxy-2-butanone over a range of temperature has been reported to form various flavor compounds.

Application

Ammonium sulfide solution may be used to enhance the performance of type-II InAs/GaSb super lattice photodiodes by surface passivation technique.


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signalword

Danger

supp_hazards

Storage Class

3 - Flammable liquids

pictograms

CorrosionEnvironment

hcodes

Hazard Classifications

Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品

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Carpenter MS, et al.
J. Vac. Sci. Technol. B, 7(4), 845-850 (1989)
Mild method for the conversion of amides to thioamides.
Charette AB and Grenon M.
The Journal of Organic Chemistry, 68(14), 5792-5794 (2003)
Ammonium sulfide passivation of Type-II InAs/GaSb superlattice photodiodes.
Gin A, et al.
Applied Physics Letters, 84(12), 2037-2039 (2004)



Global Trade Item Number

SKUGTIN
515809-100ML04061832500256
515809-500ML04061832500454
515809-4X100ML04061837634338