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Merck
CN

62615

Lithium metaborate

purum p.a., anhydrous, molar ratio (B2O3/Li2O): 0.95-1.05

Synonym(s):

Boric acid lithium salt

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About This Item

Linear Formula:
LiBO2
CAS Number:
Molecular Weight:
49.75
UNSPSC Code:
12352302
PubChem Substance ID:
EC Number:
236-631-5
MDL number:
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InChI key

HZRMTWQRDMYLNW-UHFFFAOYSA-N

InChI

1S/BO2.Li/c2-1-3;/q-1;+1

SMILES string

[Li+].[O-]B=O

grade

purum p.a.

quality

molar ratio (B2O3/Li2O): 0.95-1.05

loss

≤2% loss on ignition, 400 °C

mp

845 °C (lit.)

anion traces

sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg, Cd: ≤50 mg/kg, Co: ≤50 mg/kg, Cu: ≤50 mg/kg, Fe: ≤50 mg/kg, K: ≤100 mg/kg, Na: ≤100 mg/kg, Ni: ≤50 mg/kg, Pb: ≤50 mg/kg, Zn: ≤50 mg/kg

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General description

Lithium metaborate (LiBO2) is the lithium salt of boric acid. It can be synthesized by reacting orthoboric acid with lithium carbonate. Its crystals belong to the monoclinic crystal system having space group P21/c. Three polymorphic forms have been identified on ambient pressure devitrification of LiBO2: α-, γ- and β′-LiBO2.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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The devitrification of lithium metaborate: polymorphism and glass formation.
Chryssikos GD, et al.
Journal of Non-Crystalline Solids, 126(1), 42-51 (1990)
The crystal structure of lithium metaborate.
Zachariasen WH.
Acta Crystallographica, 17(6), 749-751 (1964)
M Ceretti et al.
Radiation protection dosimetry, 144(1-4), 262-265 (2011-02-08)
This work summarises the results of a series of experiences made on Panasonic UD-802AS, a multi-element dosemeter that is currently used in Caorso Nuclear Power Plant for personnel external monitoring. Two main topics have been considered: energy response and the
Frank R Wagner et al.
Optics express, 18(26), 26791-26798 (2011-01-05)
Multiple pulse nanosecond laser induced damage in the bulk of LiB3O5 (LBO) crystals was investigated at 1064 nm, 532 nm and 355 nm. Scanning electron microscopy of cleaved damage sites confirmed the presence of different zones that have already been
J Graetz et al.
Nanotechnology, 20(20), 204007-204007 (2009-05-08)
The local bonding and atomic environments in the Ni-catalyzed destabilized system LiBH4/MgH2 and the quaternary borohydride-amide phase Li3BN2H8, were studied by x-ray absorption spectroscopy. In both cases the Ni catalyst was introduced as NiCl2 and a qualitative comparison of the

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