63102
Magnesium perchlorate
puriss., free-flowing powder, ≥99.0% (calc. based on dry substance, KT)
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About This Item
Linear Formula:
Mg(ClO4)2
CAS Number:
Molecular Weight:
223.21
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
233-108-3
MDL number:
Assay:
≥99.0% (calc. based on dry substance, KT)
Form:
free flowing powder
InChI key
MPCRDALPQLDDFX-UHFFFAOYSA-L
InChI
1S/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2
SMILES string
[Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
grade
puriss.
assay
≥99.0% (calc. based on dry substance, KT)
form
free flowing powder
quality
free-flowing powder
impurities
≤8% water
storage temp.
room temp
Quality Level
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General description
Magnesium perchlorate (Mg(ClO4)2) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l.
Application
Magnesium perchlorate (Mg(ClO4)2) may be employed as a catalyst in the following studies:
- Preparation of a-aminophosphonates.
- Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one.
- Preparation of imines and phenylhydrazones.
- Protection of alcohols in the form of t-butyl ethers.
filler for drying tubes (especially for elemental analysis)
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
危险化学品
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The first enantioselective synthesis of both Diels-Alder enantiomers with the same bis (oxazoline)-magnesium perchlorate chiral catalyst.
Desimoni G, et al.
Tetrahedron Letters, 37(17), 3027-3030 (1996)
T Theophanides
Magnesium research, 9(4), 259-262 (1996-12-01)
The interaction of Mg2+ cations in biological systems is studied by using nucleic acid bases as the biological system. Magnesium salts, such as, MgCl2 6H2O, MgSO4. 7H2O and Mg(ClO4). XH2O have been employed in order to compare their complexation with
K Miyake et al.
Photochemistry and photobiology, 58(5), 631-636 (1993-11-01)
We have investigated the photosensitized monomerization of the cis,syn-cyclobutane dimer of 1,3-dimethylthymine using riboflavin tetraacetate and a 5-deazaflavin derivative as photosensitizer. Although little monomerization of the dimer is induced by photoexcitation of the flavins in the absence of any additives
Magnesium perchlorate as an efficient catalyst for the synthesis of imines and phenylhydrazones.
Chakraborti AK, et al.
Tetrahedron Letters, 45(41), 7641-7644 (2004)
Eagleson M.
Concise Encyclopedia Chemistry, 343-343 (1994)
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