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Merck
CN

72260

Nickel(II) perchlorate hexahydrate

purum p.a., crystallized, ≥98.0% (KT)

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About This Item

Linear Formula:
Ni(ClO4)2 · 6H2O
CAS Number:
Molecular Weight:
365.69
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
237-124-1
MDL number:
Assay:
≥98.0% (KT)
Form:
crystals
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InChI key

WHGYCGOFTBFDLW-UHFFFAOYSA-L

InChI

1S/2ClHO4.Ni.6H2O/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);;6*1H2/q;;+2;;;;;;/p-2

SMILES string

O.O.O.O.O.O.[Ni++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

grade

purum p.a.

assay

≥98.0% (KT)

form

crystals

quality

crystallized

reaction suitability

reagent type: oxidant

mp

140 °C (lit.)

anion traces

chloride (Cl-): ≤500 mg/kg, sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤500 mg/kg, Cd: ≤50 mg/kg, Co: ≤500 mg/kg, Cu: ≤50 mg/kg, Fe: ≤50 mg/kg, K: ≤100 mg/kg, Na: ≤200 mg/kg, Pb: ≤50 mg/kg, Zn: ≤50 mg/kg

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General description

Nickel(II) perchlorate hexahydrate is a hydrated nickel(II) salt.

Application

Nickel(II) perchlorate hexahydrate may be used in the synthesis of tris(2,2′-bipyridylamine)nickel(II) perchlorate and 4,7,7-trimethyl-3,4,5,6,7,8-hexahydrobenzopyran-2(H),5-dione.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 3 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Nickel (II)-2, 2'-dipyridylamine system. I. Synthesis and stereochemistry of the complexes.
Hurley TJ and Robinson MA.
Inorganic Chemistry, 7(1), 33-38 (1968)
A new method for enol lactone synthesis by a Michael addition/cyclization sequence.
Itoh K and Kanemasa S.
Tetrahedron Letters, 44(9), 1799-1802 (2003)

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