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Merck
CN

79622

Sigma-Aldrich

Phosphoric acid

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puriss. p.a., crystallized, ≥99.0% (T)

Synonym(s):

Orthophosphoric acid

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About This Item

Linear Formula:
H3PO4
CAS Number:
7664-38-2
Molecular Weight:
98.00
Beilstein:
1921286
EC Number:
231-633-2
MDL number:
MFCD00011340
UNSPSC Code:
12352106
PubChem Substance ID:
329768533
NACRES:
NA.21

Key Documents

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vapor density

3.4 (vs air)

Quality Level

200

vapor pressure

2.2 mmHg ( 20 °C)
5 mmHg ( 25 °C)

grade

puriss. p.a.

Assay

≥99.0% (T)

form

powder or crystals

quality

crystallized

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impurities

≤0.002% KMnO4-reducing matter (as O)

bp

158 °C (lit.)

mp

~40 °C (lit.)
~40 °C

solubility

water: 850 g/L at 20 °C

density

1.685 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤5 mg/kg
nitrate (NO3-): ≤5 mg/kg
phosphite, hypophosphite (as H3PO3): ≤500 mg/kg
sulfate (SO42-): ≤30 mg/kg

cation traces

As: ≤1 mg/kg
Ca: ≤10 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤10 mg/kg
K: ≤5 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Na: ≤50 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Zn: ≤1 mg/kg

greener alternative category

Enabling

SMILES string

OP(O)(O)=O

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

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General description

Phosphoric acid (H3PO4) is also known as orthophosphoric acid. It serves as an intermediary or reagent in various manufacturing processes.
The product is crystalline phosphoric acid.
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Application

Phosphoric acid has been employed as an oxidation reagent in a study.1 It may be used in the preparation of ammonium phosphate.
Phosphoric acid is used:
  • As a catalyst in the nucleophilic addition to imines.
  • In the synthesis of porous phosphoric acid-based geopolymers.
  • In the synthesis of mono-alkyl phosphates from simple aliphatic alcohols in the presence of acetic anhydride activator.

Other Notes

Concentrated phosphoric acid is approx. 85% H3PO4 (aqueous).

Disclaimer

product may become solid, becomes liquid on heating to 50°C

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H290,H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCN7172
BCCN1870
BCCM7792
BCCL4861
BCCL9881

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Eagleson M.
Concise Encyclopedia Chemistry, 67-67 (1994)
Li Yan Chan et al.
The Journal of organic chemistry, 78(17), 8826-8832 (2013-08-07)
A simple and efficient method is developed for Pd-catalyzed ortho-acetoxylation using organophosphates, namely, benzylic phosphonic and aryl phosphoric monoacids, as the directing group.
Amit Kumar Sinha et al.
PloS one, 9(4), e95319-e95319 (2014-04-18)
Oxidative stress and the antioxidant response induced by high environmental ammonia (HEA) were investigated in the liver and gills of three freshwater teleosts differing in their sensitivities to ammonia. The highly ammonia-sensitive salmonid Oncorhynchus mykiss (rainbow trout), the less ammonia
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