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Merck
CN

85140

Silver acetate

purum p.a., ≥99.0% (T)

Synonym(s):

Acetic acid silver salt

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About This Item

Linear Formula:
CH3COOAg
CAS Number:
Molecular Weight:
166.91
UNSPSC Code:
12352300
NACRES:
NA.21
PubChem Substance ID:
EC Number:
209-254-9
Beilstein/REAXYS Number:
3595636
MDL number:
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InChI key

CQLFBEKRDQMJLZ-UHFFFAOYSA-M

InChI

1S/C2H4O2.Ag/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

SMILES string

CC(O[Ag])=O

grade

purum p.a.

assay

≥99.0% (T)

form

powder

anion traces

sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤50 mg/kg, Cd: ≤50 mg/kg, Co: ≤50 mg/kg, Cu: ≤50 mg/kg, Fe: ≤50 mg/kg, K: ≤150 mg/kg, Na: ≤100 mg/kg, Ni: ≤50 mg/kg, Pb: ≤50 mg/kg, Zn: ≤50 mg/kg

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General description

Reaction of silver carbonate with acetic acid at 45-60°C has been reported to afford silver acetate. It participates in the conversion of carboxylic acid chlorides to amides, via aminolysis.

Application

Silver acetate may be used in the synthesis of α-cis glycol and β-cis glycol. It may be used as a catalyst in the synthesis of Δ1- or Δ2-pyrrolines.
Used in a novel preparation of highly reflective, conductive silvered polymer films. Also effectively catalyzes cycloaddition reactions of isocyanoacetates with a variety of olefins.

pictograms

Exclamation markEnvironment

signalword

Warning

Hazard Classifications

Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Study of thermal decomposition of silver acetate.
Logvinenko V, et al.
Journal of Thermal Analysis and Calorimetry, 90(3), 813-816 (2007)
cis-Hydroxylation of a synthetic steroid intermediate with iodine, silver acetate and wet acetic acid.
Woodward RB and Brutcher Jr FV.
Journal of the American Chemical Society, 80(1), 209-211 (1958)
Silver acetate-assisted formation of amides from acyl chlorides.
Leggio A, et al.
Tetrahedron Letters, 56(1), 199-202 (2015)
U Lorenz et al.
European journal of vascular and endovascular surgery : the official journal of the European Society for Vascular Surgery, 41(1), 68-75 (2010-10-15)
Biophotonic imaging was compared to standard enumeration method both for counting Staphylococcus aureus in biofilm and bacterial susceptibility tests of different graft materials. Prospective, randomized, controlled animal study. Five types of vascular grafts were placed subcutaneously in 35 mice and
Zi-Qiang Wang et al.
Huan jing ke xue= Huanjing kexue, 32(1), 145-150 (2011-03-17)
Activated carbon-silver composite (Ag/AC) for antibacterial performance by controlling silver release was prepared by silver acetate vacuum impregnation method. The antibacterial activity towards E. coil and resistance of water erosion was investigated through distilled water. Surface area and porosity analyzer

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