25102
9-(Chloromethyl)anthracene
BioReagent, suitable for fluorescence, ≥97.0% (AT)
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About This Item
Empirical Formula (Hill Notation):
C15H11Cl
CAS Number:
Molecular Weight:
226.70
EC Number:
246-274-7
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
1873394
MDL number:
InChI key
PCVRSXXPGXRVEZ-UHFFFAOYSA-N
InChI
1S/C15H11Cl/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9H,10H2
SMILES string
ClCc1c2ccccc2cc3ccccc13
product line
BioReagent
assay
≥97.0% (AT)
mp
138-140 °C (lit.)
fluorescence
λex 356 nm; λem 412 nm (after derivatisation with sodium acetate)
suitability
suitable for fluorescence
Analysis Note
In addition to the emission maximum at 412 nm, there are lower maxima at 434, 395 and 459 nm.
Other Notes
Blocking group reagent for carboxylic acids, phenols, thiophenols and mercaptans; Derivatizing agent for carboxylic acids giving esters with enhanced UV and fluorescence detection in HPLC
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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W.D. Korte
Journal of Chromatography A, 243, 153-153 (1982)
Jason P Schrum et al.
Journal of the American Chemical Society, 131(40), 14560-14570 (2009-09-18)
The development of a sequence-general nucleic acid copying system is an essential step in the assembly of a synthetic protocell, an autonomously replicating spatially localized chemical system capable of spontaneous Darwinian evolution. Previously described nonenzymatic template-copying experiments have validated the
Dorothea F K Rawn et al.
Journal of chromatography. A, 1080(2), 148-156 (2005-07-13)
A rapid and simple method for confirmation of the diarrhetic shellfish poisons (DSP): okadaic acid (OA), dinophysistoxin-1 (DTX-1) and dinophysistoxin-2 (DTX-2) using fluorescence detection following derivatization with 9-chloromethylanthracene, has been established as an alternate to LC/MS. Exposure of the anthrylmethyl
Ying Zhang et al.
Colloids and surfaces. B, Biointerfaces, 44(2-3), 104-109 (2005-07-26)
Polymeric micelles based on amphiphilic diblock copolymers methoxy poly(ethylene glycol)-polylactide with various hydrophobic lengths were designed as carriers of poorly water-soluble anticancer drug methotrexate (MTX). Relationship between physicochemical characteristics of micelles and release behavior was explored. The critical micelle concentration
Zhenming Xie et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 857(1), 53-58 (2007-08-21)
A rapid and sensitive RP-HPLC method with fluorescence detection has been developed for the quantitative analysis of trace amounts of monofluoroacetate (MFA) in biological samples as serum, food and meat. 9-Chloromethylanthracene (9-CMA) is used as the fluorescence labeling reagent. Samples
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