40559
3-Piperonylcyclobutanone
≥98.0% (HPLC)
Synonym(s):
3-(1,3-Benzodioxol-5-ylmethyl)cyclobutanone, 3-(3,4-Methylenedioxybenzyl)cyclobutanone
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About This Item
Empirical Formula (Hill Notation):
C12H12O3
CAS Number:
Molecular Weight:
204.22
NACRES:
NA.25
PubChem Substance ID:
UNSPSC Code:
12352200
MDL number:
Assay:
≥98.0% (HPLC)
Form:
liquid
InChI key
AWAOUJUBBHDZRM-UHFFFAOYSA-N
SMILES string
O=C1CC(C1)Cc2ccc3OCOc3c2
InChI
1S/C12H12O3/c13-10-4-9(5-10)3-8-1-2-11-12(6-8)15-7-14-11/h1-2,6,9H,3-5,7H2
assay
≥98.0% (HPLC)
form
liquid
Application
3-Piperonylcyclobutanone may be used as a reagent in the chiral synthesis of lignan lactones such as (-)-hinokinin, (-)-deoxypodorhizone, (-)-isohibalactone and (-)-savinin.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
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Chiral synthesis of lignan lactones, (?)-hinokinin, (?)-deoxypodorhizone, (?)-isohibalactone and (?)-savinin by means of enantioselective deprotonation strategy.
Toshio Honda, Nobuaki Kimura,
Journal of the Chemical Society. Perkin Transactions 1, 1, 1043-1046 (1994)
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