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Merck
CN

62579

Lithium perchlorate

BioUltra, ≥99.0% (calc. based on dry substance, T)

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About This Item

Linear Formula:
LiClO4
CAS Number:
Molecular Weight:
106.39
UNSPSC Code:
12352200
PubChem Substance ID:
EC Number:
232-237-2
MDL number:
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product line

BioUltra

assay

≥99.0% (calc. based on dry substance, T)

impurities

insoluble matter, passes filter test, ≤3% water

pH

6.0-9.5 (25 °C, 1 M in H2O)

mp

236 °C (lit.)

solubility

H2O: 1 M at 20 °C, clear, colorless

anion traces

chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤50 mg/kg

cation traces

Al: ≤5 mg/kg, As: ≤0.1 mg/kg, Ba: ≤5 mg/kg, Bi: ≤5 mg/kg, Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤20 mg/kg, Mn: ≤5 mg/kg, Mo: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Sr: ≤5 mg/kg, Zn: ≤5 mg/kg

λ

1 M in H2O

UV absorption

λ: 260 nm Amax: ≤0.037, λ: 280 nm Amax: ≤0.032

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

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Application

Lithium perchlorate may be useful as a component in the development of biopolymers and biofilms. Lithium perchlorate is a useful reagent in synthetic processes and protein analysis.

Physical form

powder or fine crystals

Other Notes

An effective protein denaturant

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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S Maruyama et al.
Biochimica et biophysica acta, 494(2), 343-353 (1977-10-26)
In an attempt to understand the specific effect of inorganic protein denaturants, lithium cation and perchlorate anion, upon the molecular conformation of bovine alpha-lactalbumin and to characterize the denatured states of the protein and the denaturation processes, themodynamic studies on
S Fuentes et al.
Biomacromolecules, 1(2), 239-243 (2001-11-17)
Chitosan/poly(aminopropylsiloxane) hybrid films were obtained by blending 3-(aminopropyl)siloxane oligomers (pAPS) with chitosan (CHI). The pAPS oligomers were prepared by the sol-gel method starting from 3-(aminopropyl)triethoxysilane. These hybrids were characterized by chemical, spectroscopic and morphological methods. Scanning electron micrographs of hybrid
A comparison of the denatured states of alpha-lactalbumin and lysozyme.
R N Sharma et al.
Journal of molecular biology, 88(1), 247-257 (1974-09-05)
J Torres et al.
Biophysical journal, 68(5), 2049-2055 (1995-05-01)
Fourier transform infrared and UV fourth-derivative spectroscopies were used to study the secondary structure of bacteriorhodopsin and its chymotryptic and one of the sodium borohydride fragments dissolved in chloroform-methanol (1:1, v/v), 0.1 M LiClO4. The C1 fragment (helices C, D
Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave

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