66950
Methyl-β-D-glucopyranoside hemihydrate
≥99.0% (sum of enantiomers, HPLC)
Synonym(s):
β-Methyl-D-glucoside hemihydrate
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About This Item
Empirical Formula (Hill Notation):
C7H14O6 · 0.5H2O
CAS Number:
Molecular Weight:
203.19
UNSPSC Code:
12352201
NACRES:
NA.25
PubChem Substance ID:
EC Number:
211-909-9
Beilstein/REAXYS Number:
81567
MDL number:
assay
≥99.0% (sum of enantiomers, HPLC)
optical activity
[α]20/D −33±1°, c = 10% in H2O
mp
107-111 °C
solubility
H2O: 0.1 g/mL, clear, colorless
SMILES string
CO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O
InChI
1S/C7H14O6/c1-12-7-6(11)5(10)4(9)3(2-8)13-7/h3-11H,2H2,1H3/t3-,4-,5+,6-,7-/m1/s1
InChI key
HOVAGTYPODGVJG-XUUWZHRGSA-N
Application
Methyl-β-D-glucopyranoside is used as a starting material for the biosynthesis of long-chain alkyl glucosides. Methyl-β-D-glucopyranoside is used as a substrate to identify, differentiate and characterize β-D-glucosidase(s).
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
涉药品监管产品
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S Aubert et al.
Journal of experimental botany, 55(406), 2179-2189 (2004-09-14)
Using (13)C-NMR, methyl-beta-D-glucopyranoside (MeG) was characterized as a major compound in the leaves of the alpine herb Geum montanum L. MeG continuously accumulated during the life span of G. montanum leaves, and accounted for up to 20% of the soluble
Methyl glucoside hydrolysis catalyzed by β-glucosidase.
Golden EB, Byers LD.
Biochimica et Biophysica Acta, 1794, 1643-1647 (2099)
Mohd Younis Rather et al.
Bioresource technology, 107, 287-294 (2012-01-10)
In the present study, we have investigated the use of Pichia etchellsii whole cells for synthesis of long-chain alkyl glucosides. Methyl-β-d-glucopyranoside (MG) was used in reaction with fatty alcohols, n-hexanol, n-octanol, n-decanol and n-dodecanol to synthesize the respective alkyl glucosides.
Mohd Younis Rather et al.
Journal of biotechnology, 150(4), 490-496 (2010-10-12)
Octyl-β-D-glucopyranoside was synthesized by transglucosylation between p-nitrophenyl β-D-glucopyranoside (pNPG) and octanol as an acceptor using whole cells of thermo tolerant yeast Pichia etchellsii displaying cell wall bound β-glucosidase. Effect of several parameters such as glucosyl donor concentration, enzyme units and
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