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Merck
CN

C8268

Cesium fluoride

≥99.9%

Synonym(s):

NSC 84270

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About This Item

Empirical Formula (Hill Notation):
CsF
CAS Number:
Molecular Weight:
151.90
EC Number:
236-487-3
UNSPSC Code:
12352103
MDL number:
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assay

≥99.9%

mp

682 °C (lit.)

density

4.115 g/mL at 25 °C (lit.)

absorption

<0.2 at 280 in H2O at 50%

SMILES string

[F-].[Cs+]

InChI

1S/Cs.FH/h;1H/q+1;/p-1

InChI key

XJHCXCQVJFPJIK-UHFFFAOYSA-M

Application

Reactant for:
  • Preparation of building blocks for synthesis of fluoroallylic compounds
  • Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions
  • Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds
  • Nucleophilic aromatic substitution (SNAr) reactions
Used in the successful synthesis of a single-crystal Dion-Jacobson phase, CsLaTa2O7, that has applications in photocatalysis and superconductivity.

Analysis Note

Yields a clear colorless solution.


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