G1141
Gly-Gly benzyl ester p-toluenesulfonate salt
≥98%
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About This Item
Empirical Formula (Hill Notation):
C11H14N2O3 · C7H8O3S
CAS Number:
Molecular Weight:
394.44
UNSPSC Code:
12352209
PubChem Substance ID:
NACRES:
NA.26
MDL number:
Product Name
Gly-Gly benzyl ester p-toluenesulfonate salt,
assay
≥98%
form
powder
color
white
application(s)
peptide synthesis
storage temp.
2-8°C
SMILES string
Cc1ccc(cc1)S(O)(=O)=O.NCC(=O)NCC(=O)OCc2ccccc2
InChI
1S/C11H14N2O3.C7H8O3S/c12-6-10(14)13-7-11(15)16-8-9-4-2-1-3-5-9;1-6-2-4-7(5-3-6)11(8,9)10/h1-5H,6-8,12H2,(H,13,14);2-5H,1H3,(H,8,9,10)
InChI key
RWBJLSORGVEMHA-UHFFFAOYSA-N
Application
Gly-Gly benzyl ester p-toluenesulfonate salt may be used as an organic intermediate in peptide synthetic processes.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Munetaka Kunishima et al.
Chemical & pharmaceutical bulletin, 50(4), 549-550 (2002-04-20)
Racemization of the C-terminal amino acid (Ala) has been studied in various solvents during coupling between 4-methoxybenzyloxycarbonyl (Z(OMe))-Gly-L-Ala-OH and phenylalanine benzyl ester (H-Phe-OBzl) with 4-(4,6-dimethoxy-1,3,5-thiazin-2-yl)-4-methylmorpholinium chloride (DMT-MM). The reaction occurred without substantial racemization in AcOEt, tetrahydrofuran (THF), N,N-dimethylformamide (DMF), CH3CN
Dawei Ma et al.
Organic letters, 4(14), 2377-2380 (2002-07-06)
[reaction: see text] Condensation of L-valine benzyl ester toluenesulfonic acid salt with a substituted cyclohexadione followed by aromatization with the assistance of NBS provides an N-aryl L-valine benzyl ester. This intermediate is converted into 7-substituted benzolactam-V8s using an asymmetric Strecker
Global Trade Item Number
| SKU | GTIN |
|---|---|
| G1141-5G | 04061832888606 |
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