G1513
Glycerol formal
47-67% 5-hydroxy-1,3-dioxane basis (GC), 33-53% 4-hydroxymethyl-1,3-dioxolane basis (GC)
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About This Item
Empirical Formula (Hill Notation):
C4H8O3
CAS Number:
Molecular Weight:
104.10
UNSPSC Code:
50161901
NACRES:
NA.25
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
103206
InChI key
JIUMSISXCKWZTA-UHFFFAOYSA-N
SMILES string
OCC1COCO1.OC2COCOC2
InChI
1S/2C4H8O3/c5-4-1-6-3-7-2-4;5-1-4-2-6-3-7-4/h2*4-5H,1-3H2
contains
~0.02% 2,6-di-tert-butyl-4-methylphenol as stabilizer
composition
5-hydroxy-1,3-dioxane, 47-67% GC , 4-hydroxymethyl-1,3-dioxolane, 33-53% GC
bp
192-193 °C (lit.)
density
1.203 g/mL at 25 °C (lit.)
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General description
Glycerol formal (GlyF) includes isomers, namely, 4-hydroxymethyl-1,3-dioxolane and 5-hydroxy-1,3-dioxane. It is a glycerol synthon with a combination of two 5- and 6-membered ring isomers.
Application
Glycerol formal is used to to solubilize water-insoluble compounds for subsequent aqueous dilution. It has been used as a chemical and dye emulsifier and as a cosolvent for drug delivery
Glycerol formal is used to to solubilize water-insoluble compounds for subsequent aqueous dilution. It has been used as a chemical and dye emulsifier and as a cosolvent for drug delivery. Glycerol formal was used as a vehicle for antibiotic delivery in rats.
wgk
WGK 3
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Selective catalytic etherification of glycerol formal and solketal with dialkyl carbonates and K 2 CO 3
Selva M, et al.
Green Chemistry, 188-200 (2012)
Properties of fatty acid glycerol formal ester (FAGE) for use as a component in blends for diesel engines
Lapuerta M, et al.
Biomass and Bioenergy, 130-140 (2015)
Sarah Nickolls et al.
Advances in pharmacological sciences, 2011, 608912-608912 (2011-12-14)
GABA(A) receptors containing α2/3 subunits are current targets in the battle to develop new pain medications, as they are expressed in the spinal cord where increasing inhibitory drive should result in analgesia. However, this approach is prone to a range
Kazuo Hotta et al.
Anticancer research, 35(9), 4681-4689 (2015-08-09)
We investigated whether hepatic multidrug resistance-associated protein 2 (ABCC2) is involved in the hepatobiliary excretion of regorafenib, a novel multi-kinase inhibitor, using Sprague-Dawley (SD) rats and Eisai hyperbilirubinemic rats (EHBR) lacking the efflux transporter ABCC2. The involvement of organic anion-transporting
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