10464-U
Carbopack™ Adsorbent
matrix Carbopack™ Y, 120-400 mesh, bottle of 50 g
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About This Item
UNSPSC Code:
23201100
EC Number:
215-609-9
NACRES:
SB.54
product line
Carbopack™
form
granular
packaging
bottle of 50 g
technique(s)
LPLC: suitable
surface area
~24 m2/g
matrix
Carbopack™ Y
matrix active group
carbon
particle size
120-400 mesh
pore size
~0 cm3/g macroporosity, ~0 cm3/g mesoporosity, ~0 cm3/g microporosity, ~0 Å pore diameter
density
~0.38 g/mL (free fall density)
separation technique
reversed phase
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General description
A graphitized carbon black (GCB) can be non-porous or porous. The graphitization process results in a highly pure surface with great adsorption and desorption (if required) properties. Surface interactions depend solely on dispersion (London) forces. These particles are:
Generally, GCB adsorbents offer weaker relative adsorptive strength compared to carbon molecular sieve (CMS) adsorbents, and similar relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) adsorbents. Our Carbopack products are a type of GCB adsorbent.
For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon
- Granular
- Friable
- Used for molecules with an analyte size relative to C3-C20+ n-alkanes
- Hydrophobic (can be used in high humidity environments)
Generally, GCB adsorbents offer weaker relative adsorptive strength compared to carbon molecular sieve (CMS) adsorbents, and similar relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) adsorbents. Our Carbopack products are a type of GCB adsorbent.
- Particles are 40 mesh and smaller
- Use 40/60 mesh to prevent channeling (if observed with a 20/40 mesh Carbotrap® adsorbent)
- Use smaller mesh (60/80, 80/100, etc.) for all other applications
- Use the smallest particle size available as long as the application can handle the pressure drop
For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon
Carbotrap®/Carbopack™ adsorbent can withstand high bake-out temperature without losing the mechanical and chemical integrity. It has a high affinity for isoprene and does not retain significant amounts of water. Furthermore it has a tendency to pulverize if it is packed too tightly. Carbotrap®/Carbopack™ adsorbent was used to quantitatively determine trace amounts of volatile organic compounds (VOCs) in air. It was also used for designing sampling protocols on the basis of its retention volume of the gaseous organic compounds of interest.
Application
Carbopack™ Y was used for determination of contamination caused by pesticides like alachlor, atrazine, captan, formothion, lindane and phosalone in atmospheric samples. Carbopack™ Y was modified with mono-molecular layer of heptakis-(2,3,6-tri-O-methyl)-β-cyclodextrin and was used in gas chromatography to study the effect of size and spatial structure of adsorbate molecules on adsorption of organic vapours.
Legal Information
Carbopack is a trademark of Merck KGaA, Darmstadt, Germany
Carbotrap is a registered trademark of Merck KGaA, Darmstadt, Germany
Storage Class
11 - Combustible Solids
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Gas phase retention volume behavior of organic compounds on Carbotrap graphitized carbon.
Pankow JF.
Journal of Chromatography A, 547, 488-493 (1991)
Adsorption of organic vapors on the Carbopack Y carbon adsorbent modified with heptakis-(2, 3, 6-tri-O-methyl)-?-cyclodextrin.
Kudryashov SY, et al.
Russian Journal of Physical Chemistry A, 84 (3), 495-502 (2010)
Comparison of Tenax TA and Carbotrap for sampling and analysis of volatile organic compounds in air.
Rothweiler H, et al.
Atmospheric Environment, 25 (2), 231-235 (1991)
Rybolt et al.
Journal of colloid and interface science, 220(1), 148-156 (1999-11-07)
Second gas-solid virial coefficients were determined at 403.5 +/- 0.5 K for 6 adsorbates, including butane, chloroform, trichlorofluoromethane (Freon 11), bromochloromethane, 1-chloro-2-methylpropane, and dibromodifluoromethane. For another 11 adsorbates, including dichlorodifluoromethane (Freon 12), chlorodifluoromethane (Freon 22), methyl chloride, methylene chloride, propane
Plant Volatile Analysis.
Linskens HF and Jackson JF.
Modern Methods of Plant Analysis, 19, 54-56 (1997)
Articles
Synthetic CMS carbons offer tailored adsorbents for specific applications.
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