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Merck
CN

33020-U

Supelco

BF3 - Methanol

10 % (w/w)

Synonym(s):

Boron trifluoride

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About This Item

UNSPSC Code:
12352200

Key Documents

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grade

derivatization grade ((GC derivatization))

reaction suitability

reagent type: derivatization reagent
reaction type: Alkylations
reagent type: derivatization reagent
reaction type: Esterifications

packaging

pkg of 19 × 2 mL (33020-U)

concentration

10 % (w/w)

storage temp.

2-8°C

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General description

Boron trifluoride is a colourless gas and readily reacts with water to form hydrates. It has been widely used as a catalyst during polymerizations, alkylations and condensation reactions. It is generally used as gas flux during internal soldering or brazing. It also finds application in being used a extinguisher for magnesium fires.

Application

It was used in transmethylation of 1,2-Diacylglycerol (DAG) containing fractions which were purified using HPLC. It may also be used to treat lipids during determination of fatty acid methyl esters and dimethylacetals using GC.

Other Notes

Reagent for O-acetyl, methyl ester, methyl 2,2-dimethoxypropionate, dimethyl acetals and dimethoxy.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

Target Organs

Eyes, Kidney

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

60.8 °F - closed cup

Flash Point(C)

16 °C - closed cup

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
LC22713V
LC21916V
LC21757V
LC18755V
LC17218V

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S B Bocckino et al.
The Journal of biological chemistry, 260(26), 14201-14207 (1985-11-15)
1,2-Diacylglycerol (DAG) was measured in neutral lipid extracts from isolated hepatocytes using high pressure liquid chromatography followed by refractive index detection. Maximally effective doses of epinephrine, angiotensin II, and vasopressin increased DAG by approximately 65, 80, and 180-250%, respectively, with
Separation and quantitative determination of lactic, pyruvic, fumaric, succinic, malic, and citric acids by gas chromatography.
E Hautala et al.
Analytical biochemistry, 30(1), 32-39 (1969-07-01)
J.Horner et al.
Analytical Chemistry, 46, 110-110 (1974)
B.Hallgren and S. Larsson
Journal of Lipid Research, 3, 32-32 (1962)
Florence R Danila et al.
Communications biology, 4(1), 254-254 (2021-02-28)
C4 photosynthesis provides an effective solution for overcoming the catalytic inefficiency of Rubisco. The pathway is characterised by a biochemical CO2 concentrating mechanism that operates across mesophyll and bundle sheath (BS) cells and relies on a gas tight BS compartment.
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