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Merck
CN

33021

Supelco

BF3 - Methanol

10 % (w/w), pkg of 400 mL

Synonym(s):

Boron trifluoride

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About This Item

UNSPSC Code:
41116105
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grade

derivatization grade ((GC derivatization))

reaction suitability

reagent type: derivatization reagent
reaction type: Alkylations

reagent type: derivatization reagent
reaction type: Esterifications

packaging

pkg of 400 mL

concentration

10 % (w/w)

storage temp.

2-8°C

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General description

The BF3-Methanol reagent is available commercially, BF3 is the catalyst and acidic in nature thereby making it suitable for the methylation of all lipid classes, including amides, FFAs and plasmalogens. However, the reagent is not stable and should be used fresh, else it will result in by-products. This reagent is most commonly used for the derivatization of fatty acids and for the transesterification of lipids.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

Target Organs

Eyes, Kidney

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

60.8 °F - closed cup

Flash Point(C)

16 °C - closed cup

Regulatory Information

危险化学品
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On methylation of unsaturated acids using boron trihalide-methanol reagents.
Klopfenstein WE.
Journal of Lipid Research, 12 (6), 773-776 (1971)
Practical Gas Chromatography: A Comprehensive Reference.
Wilde KD and Engewald W.
Science, 613-614 (2014)
Teaching Innovations in Lipid Science.
Weselake RJ.
Technology & Engineering, 188-189 (2007)
Separation and quantitative determination of lactic, pyruvic, fumaric, succinic, malic, and citric acids by gas chromatography.
E Hautala et al.
Analytical biochemistry, 30(1), 32-39 (1969-07-01)
J.Horner et al.
Analytical Chemistry, 46, 110-110 (1974)

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