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About This Item
EC Number:
233-892-7
UNSPSC Code:
23151816
grade
derivatization grade ((GC derivatization)), derivatization grade
reaction suitability
reagent type: derivatization reagent
reaction type: Silylations
packaging
pkg of 144 × 0.1 mL (33035-U)
General description
BSA (N,O-Bis(trimethylsilyl)acetamide) is a powerful reagent for silyation of alkyl hydroperoxides. It reacts quantitatively under mild conditions with alcohols, amines, phenols and carboxylic acids which gives trimethylsilyl ethers and esters.
Application
BSA was used in silyation procedure of amino acid phenylthiohydantoin standards during GC analysis.
Other Notes
Reagent for 1,3-dipheylimidazolidine-2-carboxylic acid, o-ethyloxime, quinoxalone, trimethylsilyl and trimethylsilyl oximes.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
111.2 °F - closed cup
flash_point_c
44 °C - closed cup
Regulatory Information
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D.R. Knapp
Handbook of Analytical Derivatization Reactions, 202-214 (1979)
Quantitative analysis of branched-chain alpha-keto acids as their trimethylsilylated oximes.
G Lancaster et al.
Clinica chimica acta; international journal of clinical chemistry, 48(3), 279-285 (1973-10-30)
Gas chromatography of some urinary acid metabolites related to phenylketonuria.
N E Hoffman et al.
Analytical biochemistry, 31(1), 471-479 (1969-10-01)
J.L. Cashaw et al.
Journal of Chromatographic Science, 9, 98-98 (1971)
Wilhelm J. Baader
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 150-150 (2014)
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