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442232-U

1,2-Diphenylhydrazine

analytical standard, ampule of 100 mg

Synonym(s):

Hydrazobenzene, N,N′-Diphenylhydrazine, N,N′-Bianiline, NSC 3510

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About This Item

Linear Formula:
C6H5NHNHC6H5
CAS Number:
122-66-7
Molecular Weight:
184.24
UNSPSC Code:
77101502
NACRES:
NA.24
PubChem Substance ID:
329756468
EC Number:
204-563-5
Beilstein/REAXYS Number:
639793
MDL number:
MFCD00003012
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grade

analytical standard

CofA

current certificate can be downloaded

packaging

ampule of 100 mg

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

mp

123-126 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-30°C

SMILES string

N(Nc1ccccc1)c2ccccc2

InChI

1S/C12H12N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10,13-14H

InChI key

YBQZXXMEJHZYMB-UHFFFAOYSA-N

General description

1,2-Diphenylhydrazine is mainly used in the manufacture of fabrics and medicines. Its other applications include, but not limited to: a precursor of benzidine, an antisludging additive for motor oil, a constituent in photochromic resins as well as in polymers, and syntheses of hydrogen peroxide (H2O2) and several dyestuffs.

Application

1,2-Diphenylhydrazine may be used as an analytical standard for the determination of the analyte in landfill leachate, pharmaceutical process stream, and aqueous solutions by high-performance liquid chromatography (HPLC) and gas chromatography (GC) based analytical techniques.
Reactant involved in:
  • Insertion reactions with organometallic tantalum complexes
  • Reduction reactions catalyzed by titanium(III) trichloride yielding amines
  • Studying the mechanism of hydrazobenzene rearrangement
  • Reaction with N-heterocyclic stable silylene
  • Synthesis of dimanganese amide hydrazide cluster complexes
  • Iron-mediated hydrazine reductions yielding iron arylimide cubanes
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

危险化学品

This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
LC26453V
LC26418V
LC24199V
LC22539V
LC08464V

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Joonas Jernberg et al.
Talanta, 103, 384-391 (2012-12-04)
Nontarget analysis means that a sample is analysed without preselection of the studied analytes. While target analysis attempts to determine whether certain selected compounds are present in the sample, nontarget analysis is performed to explore what unknown compounds can be
F Matsui et al.
Journal of pharmaceutical sciences, 72(10), 1223-1224 (1983-10-01)
A high-performance liquid chromatographic method has been developed for the simultaneous determination of azobenzene and hydrazobenzene in phenylbutazone and sulfinpyrazone raw materials and formulations. The drug raw material or formulation is shaken with 1N NaOH and n-hexane and centrifuged. The
S Ohnishi et al.
Free radical research, 32(6), 469-478 (2000-05-08)
Hydrazobenzene is carcinogenic to rats and mice and azobenzene is carcinogenic to rats. Hydrazobenzene is a metabolic intermediate of azobenzene. To clarify the mechanism of carcinogenesis by azobenzene and hydrazobenzene, we investigated DNA damage induced by hydrazobenzene, using 32P-5'-end-labeled DNA
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