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Merck
CN

46702-U

N-Nitrosodiphenylamine solution

certified reference material, 5000 μg/mL in methanol

Synonym(s):

N-Nitroso-N-phenylaniline, Diphenylnitrosamine, Diphenylnitrosoamine

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About This Item

CAS Number:
86-30-6
UNSPSC Code:
77101502
EC Number:
200-659-6

Key Documents

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InChI key

UBUCNCOMADRQHX-UHFFFAOYSA-N

InChI

1S/C12H10N2O/c15-13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

grade

certified reference material, TraceCERT®

CofA

certificate of analysis is enclosed in each package.

packaging

ampule of 1 × 1 mL

concentration

5000 μg/mL in methanol

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

environmental

format

single component solution

storage temp.

2-8°C

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Flam. Liq. 2 - STOT SE 1

target_organs

Eyes,Central nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

Regulatory Information

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Certificates of Analysis (COA)

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Junghoon Choi et al.
Water research, 36(4), 817-824 (2002-02-19)
Studies have been conducted specifically to investigate the hypothesis that N-nitrosodimethylamine (NDMA) can be produced by reactions involving monochloramine. Experiments were conducted using dimethylamine (DMA) as a model precursor. NDMA was formed from the reaction between DMA and monochloramine indicating
Oxidative remediation of diphenylamine in wastewater.
I S Jamall et al.
Bulletin of environmental contamination and toxicology, 76(4), 740-744 (2006-05-12)
S E Atawodi et al.
European journal of drug metabolism and pharmacokinetics, 15(1), 27-29 (1990-01-01)
Pharmacokinetic investigations into the biliary excretion of N-nitrosodiphenylamine given as an i.p. dose of 50 mg/kg were conducted and results compared in three animal species; rat, guinea pig and rabbit following bile duct cannulation and collection of bile in vitro.
Krzysztof Piech et al.
Journal of the American Chemical Society, 129(11), 3211-3217 (2007-03-03)
A new method for investigating the mechanisms of nitric oxide release from NO donors under oxidative and reductive conditions is presented. Based on the fragmentation of N-nitrosoamines, it allows generation and spectroscopic characterization of nitrenium cations, amide anions, and aminyl
M Zielenska et al.
Mutation research, 202(1), 269-276 (1988-11-01)
The carcinogenic nitrosamines, N-nitrosomethylaniline (NMA) and N-nitrosodiphenylamine (NDphA), which have been previously reported negative or very weakly mutagenic in the Salmonella/microsome assay, were found to be mutagenic in the hisG428 Salmonella strain, TA104. NMA was moderately potent and NDphA was
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