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Merck
CN

4S8486

Vinyl acetate

analytical standard

Synonym(s):

Acetoxyethylene

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About This Item

Linear Formula:
CH3CO2CH=CH2
CAS Number:
108-05-4
Molecular Weight:
86.09
UNSPSC Code:
77101502
NACRES:
NA.24
PubChem Substance ID:
329757555
EC Number:
203-545-4
Beilstein/REAXYS Number:
1209327
MDL number:
MFCD00008713

Key Documents

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InChI key

XTXRWKRVRITETP-UHFFFAOYSA-N

InChI

1S/C4H6O2/c1-3-6-4(2)5/h3H,1H2,2H3

SMILES string

CC(=O)OC=C

grade

analytical standard

agency

EPA 8240,8260

vapor density

3 (vs air)

vapor pressure

88 mmHg ( 20 °C)

description

Separate Source

CofA

current certificate can be downloaded

autoignition temp.

801 °F

feature

standard type calibration

expl. lim.

13.4 %

packaging

pkg of 1 × 100 mg (4S8486)

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

bp

72-73 °C (lit.)

mp

−93 °C (lit.)

density

0.934 g/mL at 25 °C (lit.)

application(s)

environmental
petroleum

format

neat

storage temp.

2-8°C

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General description

Vinyl acetate is an important vinyl ester, also known as vinyl acetate monomer. It is mainly used in the production of polymers and copolymers, for coating paints, binders, textile, and paper processing industries.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Vinyl acetate is used in the production of polyvinyl acetates, ethylene vinyl acetates for use in textiles, coating and as a PVC alternative respectively.

Other Notes

Contains 3-20 ppm hydroquinone as an inhibitor
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Carc. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

17.6 °F - closed cup

flash_point_c

-8 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
LC23030V
LC20969V
LC20050V
LC17881V
LC12222V

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Francesca Reineri et al.
Nature communications, 6, 5858-5858 (2015-01-06)
The advent of nuclear spins hyperpolarization techniques represents a breakthrough in the field of medical diagnoses by magnetic resonance imaging. Dynamic nuclear polarization (DNP) is the most widely used method, and hyperpolarized metabolites such as [1-(13)C]-pyruvate are shown to report
Matthew S Bogdanffy et al.
Toxicology letters, 140-141, 83-98 (2003-04-05)
Understanding the mode of action of carcinogens is critical to scientifically assessing exposure-related risk. Regulatory hazard classification schemes and dose-response assessment paradigms generally require basic knowledge of genotoxic potential to guide decisions on which scheme or paradigm is most appropriate.
Mutagenicity studies on styrene and vinyl acetate.
H Norppa et al.
Annals of the New York Academy of Sciences, 534, 671-678 (1988-01-01)
Akifumi Nakamura et al.
Journal of the American Chemical Society, 134(30), 12366-12369 (2012-07-25)
Utilization of palladium catalysts bearing a P-chiral phosphine-sulfonate ligand enabled asymmetric copolymerization of vinyl acetate with carbon monoxide. The obtained γ-polyketones have head-to-tail and isotactic polymer structures. The origin of the regio- and stereoregularities was elucidated by stoichiometric reactions of
S Copelli et al.
Journal of hazardous materials, 192(1), 8-17 (2011-06-03)
Fast and exothermic discontinuous emulsion polymerization processes are particularly difficult to optimize from both safety and productivity point of view because of the occurrence of side undesired reactions (e.g. chain transfer to monomer, backbiting, propagation of tertiary radicals, termination by
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