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PS1051

Glyphosate

analytical standard

Synonym(s):

N-(Phosphonomethyl)glycine, Glyphosate

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About This Item

Linear Formula:
(HO)2P(O)CH2NHCH2CO2H
CAS Number:
1071-83-6
Molecular Weight:
169.07
EC Number:
213-997-4
UNSPSC Code:
41116107
MDL number:
MFCD00055350
Beilstein/REAXYS Number:
2045054
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grade

analytical standard

packaging

ampule of 1000 mg

manufacturer/tradename

Chem Service, Inc. PS-1051

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

mp

230 °C (dec.) (lit.)

application(s)

agriculture
environmental

format

neat

SMILES string

OC(=O)CNCP(O)(O)=O

InChI

1S/C3H8NO5P/c5-3(6)1-4-2-10(7,8)9/h4H,1-2H2,(H,5,6)(H2,7,8,9)

InChI key

XDDAORKBJWWYJS-UHFFFAOYSA-N

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General description

Glyphosate is a commonly used herbicide against a wide range of annual and perennial weeds.

Application

Glyphosate may be used as a reference standard for the determination of glyphosate and its metabolite aminomethylphosphonic acid in fruit juices using a supported-liquid membrane in combination with high-performance liquid chromatography and UV detection after derivatization with p-toluenesulphonyl chloride.
Purity determined by HPLC C18 method.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Aquatic Chronic 2 - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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The herbicide glyphosate.
Malik J, et al.
Biofactors, 2(1), 17-25 (1989)
Maxim V Khrolenko et al.
Journal of chromatography. A, 1093(1-2), 111-117 (2005-10-20)
The application of supported-liquid membrane (SLM) technique for effective extraction of N-(phosphonomethyl)glycine (glyphosate) and its primary metabolite aminomethylphosphonic acid (AMPA) from juices (orange, grapefruit, apple and blackcurrant) in combination with HPLC-UV detection after derivatization with p-toluenesulphonyl chloride (TsCl) is presented.
Martin M Vila-Aiub et al.
Pest management science, 69(2), 228-232 (2012-12-21)
Glyphosate resistance in populations of the C(4) perennial Sorghum halepense (Johnsongrass) and C(3) annual Lolium rigidum (rigid ryegrass) has evolved and been documented in many cropping areas around the globe. In S. halepense and in the majority of reported cases
C Lanctôt et al.
Aquatic toxicology (Amsterdam, Netherlands), 140-141, 48-57 (2013-06-12)
Amphibian tadpoles develop in aquatic environments where they are susceptible to the effects of pesticides and other environmental contaminants. Glyphosate-based herbicides are currently the most commonly used herbicide in the world and have been shown to affect survival and development
Juliana Zomer Sandrini et al.
Aquatic toxicology (Amsterdam, Netherlands), 130-131, 171-173 (2013-02-16)
Although the herbicide glyphosate [N-(phosphonomethyl)glycine] is not classified as an acethylcholinesterase inhibitor, some studies have reported reduction in the acethylcolinesterase activity after in vivo exposure to both its pure form and its commercial formulations. Considering this controversy, the objective of
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