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About This Item
Empirical Formula (Hill Notation):
HBr
CAS Number:
Molecular Weight:
80.91
EC Number:
233-113-0
UNSPSC Code:
12352106
PubChem Substance ID:
Beilstein/REAXYS Number:
3587158
MDL number:
InChI key
CPELXLSAUQHCOX-UHFFFAOYSA-N
InChI
1S/BrH/h1H
SMILES string
Br
grade
ACS reagent
vapor density
2.8 (vs air)
vapor pressure
320 psi ( 21.1 °C), 8 mmHg ( 25 °C)
description
48% aqueous HBr
concentration
48%
density
1.49 g/mL at 25 °C (lit.)
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Application
Hydrobromic acid may be used as a brominating agent for the dibromination of olefins and alkynes and also α-bromination of ketones in the presence dimethyl sulfoxide as the mild oxidant.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Efficient bromination of olefins, alkynes, and ketones with dimethyl sulfoxide and hydrobromic acid.
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The orientation dependence of Br-atom formation in the reaction of the oriented OH radical with the HBr molecule using the hexapole electrostatic field was studied. Experimental results for the orientation dependence in the reaction were analyzed using a Legendre polynomial
Małgorzata Olejniczak et al.
The Journal of chemical physics, 136(1), 014108-014108 (2012-01-14)
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