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Merck
CN

V000232

Hydrobromic acid

ACS reagent, 48%

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About This Item

Empirical Formula (Hill Notation):
HBr
CAS Number:
Molecular Weight:
80.91
EC Number:
233-113-0
UNSPSC Code:
12352106
PubChem Substance ID:
Beilstein/REAXYS Number:
3587158
MDL number:
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InChI key

CPELXLSAUQHCOX-UHFFFAOYSA-N

InChI

1S/BrH/h1H

SMILES string

Br

grade

ACS reagent

vapor density

2.8 (vs air)

vapor pressure

320 psi ( 21.1 °C), 8 mmHg ( 25 °C)

description

48% aqueous HBr

concentration

48%

density

1.49 g/mL at 25 °C (lit.)

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Application

Hydrobromic acid may be used as a brominating agent for the dibromination of olefins and alkynes and also α-bromination of ketones in the presence dimethyl sulfoxide as the mild oxidant.

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Efficient bromination of olefins, alkynes, and ketones with dimethyl sulfoxide and hydrobromic acid.
Song S, et al.
Green Chemistry, 17(6), 3285-3289 (2015)
Shujing Liang et al.
Theranostics, 5(9), 970-984 (2015-07-15)
Developing safe and effective nanoprobes for targeted imaging and selective therapy of gastric cancer stem cells (GCSCs) has become one of the most promising anticancer strategies. Herein, gold nanostars-based PEGylated multifunctional nanoprobes were prepared with conjugated CD44v6 monoclonal antibodies (CD44v6-GNS)
Arnaldur Hall et al.
Biomacromolecules, 16(7), 2119-2126 (2015-06-09)
Poly(L-lysine)s (PLLs), and related derivatives, have received considerable attention as nonviral vectors. High molecular weight PLLs (H-PLLs) are superior transfectants compared with low Mw PLLs (L-PLLs), but suggested to be more cytotoxic. Through a pan-integrated metabolomic approach using Seahorse XF
Po-Yu Tsai et al.
Physical chemistry chemical physics : PCCP, 13(4), 1419-1423 (2010-11-27)
The orientation dependence of Br-atom formation in the reaction of the oriented OH radical with the HBr molecule using the hexapole electrostatic field was studied. Experimental results for the orientation dependence in the reaction were analyzed using a Legendre polynomial
Małgorzata Olejniczak et al.
The Journal of chemical physics, 136(1), 014108-014108 (2012-01-14)
We report the implementation of nuclear magnetic resonance (NMR) shielding tensors within the four-component relativistic Kohn-Sham density functional theory including non-collinear spin magnetization and employing London atomic orbitals to ensure gauge origin independent results, together with a new and efficient

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