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Merck
CN

V000734

Nickel(II) sulfate hexahydrate

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About This Item

Linear Formula:
NiSO4 · 6H2O
CAS Number:
Molecular Weight:
262.85
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
232-104-9
MDL number:
Technical Service
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vapor density

2.07 (vs air)

SMILES string

O.O.O.O.O.O.[Ni++].[O-]S([O-])(=O)=O

InChI

1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2

InChI key

RRIWRJBSCGCBID-UHFFFAOYSA-L

Application

Nickel(II) sulfate hexahydrate (NiSO4.6H2O) can be used as a nickel precursor for the preparation of:
  • Palladium-nickel bimetallic nanoparticles (Pd-Ni B-NPs), which are used as efficient catalysts for the C-N coupling of aryl halides with amines by Buchwald–Hartwig amination reaction.
  • NiFe2O4 spinel nanoparticles by grinding with FeSO4·7H2O, and NaOH via solid-state reaction.
  • Nickel micro-flowers by chemical reduction method.

It can also be used as a recyclable catalyst in the synthesis of α-aminophosphonates by reacting with aromatic aldehyde, primary amine, and diethylphosphite by one-pot three-component reaction.


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

target_organs

Respiratory Tract

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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