V900131
CDI
Vetec™, reagent grade, 97%
Synonym(s):
1,1′-Carbonyldiimidazole
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About This Item
Empirical Formula (Hill Notation):
C7H6N4O
CAS Number:
Molecular Weight:
162.15
EC Number:
208-488-9
UNSPSC Code:
12352115
PubChem Substance ID:
Beilstein/REAXYS Number:
6826
MDL number:
InChI key
PFKFTWBEEFSNDU-UHFFFAOYSA-N
InChI
1S/C7H6N4O/c12-7(10-3-1-8-5-10)11-4-2-9-6-11/h1-6H
SMILES string
O=C(n1ccnc1)n2ccnc2
grade
reagent grade
product line
Vetec™
assay
97%
mp
117-122 °C (lit.)
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Application
CDI can be used:
- To decarboxylate malonic acid derivatives to yield carbonyl imidazole moiety, which can further be reacted with different nucleophiles.
- To activate cellulose membranes, which are used in immunosensor applications.
- To functionalize Fe3O4-SiO2 core-shell nanoparticles for bio-applications.
- To prepare syn- and anti-1,2-imidazolylpropylamines by reacting with syn- and anti-1,2-amino alcohols.
- In the preparation of N-substituted imidazole derivatives, which are further used to prepare new ionic liquids.
Legal Information
Vetec is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
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Regio-and Stereospecific Syntheses of syn-and anti-1, 2-Imidazolylpropylamines from the Reaction of 1, 1′-Carbonyldiimidazole with syn-and anti-1, 2-Amino Alcohols
Mulvihill MJ, et al.
The Journal of Organic Chemistry, 69(15), 5124-5127 (2004)
1, 1′-Carbonyldiimidazole mediates the synthesis of N-substituted imidazole derivatives from Morita--Baylis--Hillman adducts
Rodrigues Jr MT, et al.
Tetrahedron Letters, 55(1), 180-183 (2014)
Synthesis and surface functionalization of Fe3O4-SiO2 core-shell nanoparticles with 3-glycidoxypropyltrimethoxysilane and 1, 1′-carbonyldiimidazole for bio-applications
Ta TKH, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 504(2), 376-383 (2016)
Daniela Stöllner et al.
Analytical biochemistry, 304(2), 157-165 (2002-05-16)
Methods for the activation of a cellulose dialysis membrane for immunosensor applications have been developed. For activation two reagents, 1,1'-carbonyldiimidazole (CDI) and 1-cyano-4-dimethylaminopyridinium tetrafluoroborate (CDAP), were compared with respect to the coupling efficiency for glucose oxidase (GOx) and 1,8-diamino-2,6-dioxaoctane. The
Frank Münch et al.
European journal of cardio-thoracic surgery : official journal of the European Association for Cardio-thoracic Surgery, 48(2), 236-243 (2014-11-22)
Experience regarding warm blood cardioplegia according to Calafiore results from its broad use in adult patients. In this experimental study, tepid (28°C) modified full blood cardioplegia (MBC) was adopted for paediatric use and compared with cold crystalloid cardioplegia (CCC). Twenty
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