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Merck
CN

V900193

Zirconium(IV) oxychloride octahydrate

Vetec™, reagent grade, 98%

Synonym(s):

Zirconium(IV) oxide chloride, Zirconyl chloride octahydrate

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About This Item

Linear Formula:
ZrOCl2 · 8H2O
CAS Number:
13520-92-8
Molecular Weight:
322.25
UNSPSC Code:
12352302
PubChem Substance ID:
329829624
EC Number:
231-717-9
MDL number:
MFCD00149898
Assay:
98%
Grade:
reagent grade
Form:
solid

Key Documents

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Product Name

Zirconium(IV) oxychloride octahydrate, Vetec™, reagent grade, 98%

InChI key

IZYKRMGFEBSOSO-UHFFFAOYSA-L

InChI

1S/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;/q;;;;;;;;;;;+2/p-2

SMILES string

O.O.O.O.O.O.O.O.Cl[Zr](Cl)=O

grade

reagent grade

product line

Vetec™

assay

98%

form

solid

cation traces

Ti: ≤0.005%
heavy metals (as Pb): ≤0.001%

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Application

Zirconium(IV) oxychloride (ZrOCl2. 8H2O) octahydrate can be used as:     
  •   A precursor for the preparation of polyacrylamide zirconium(IV) iodate material, which is used for the removal of Pb (II) ions from wastewater.       
  • A Lewis acid catalyst to synthesize octahydroquinazolinone/thione derivatives by reacting with urea/thiourea, dimedone and aromatic aldehydes.      
  • A catalyst to synthesize amido-substituted benzo[b]furans by treating with arylglyoxals, benzamide and phenols via one-pot three-component reaction.

Legal Information

Vetec is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF1829V
WXBD7208V
WXBD4749V
WXBD1773V
WXBC7585V

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Zirconium Catalyzed Chemoselective Synthesis of New Amido-Substituted Benzo [b] furans via a One-Pot Reaction
Karami B, et al.
Heterocycles, 87(2), 399-405 (2013)
Solvent-free Synthesis of Novel and Known Octahydroquinazolinones/thiones by the Use of ZrOCl2. 8H2O as a Highly Efficient and Reusable Catalyst
Karami S, et al.
J. Chin. Chem. Soc., 60(1), 22-26 (2013)
Equilibrium modeling, kinetic, and thermodynamic studies on adsorption of Pb (II) by a hybrid inorganic-organic material: polyacrylamide zirconium (IV) iodate
Rahman N and Haseen U
Industrial & Engineering Chemistry Research, 53(19), 8198-8207 (2014)
Syed A Nabi et al.
Journal of hazardous materials, 172(1), 202-207 (2009-08-07)
Samples of zirconium(IV)iodotungstate have been synthesized under varying mixing order and ratios of aqueous solution of potassium iodate, sodium tungstate and zirconium oxychloride at pH 1. A tentative formula was proposed on the basis of chemical composition, FTIR and thermogravimetric
D Skrtic et al.
Dental materials : official publication of the Academy of Dental Materials, 12(5), 295-301 (1996-09-01)
The rationale for this study was based on the hypothesis that the mechanical strength of methacrylate composites containing the bioactive filler, amorphous calcium phosphate, can be enhanced by synthesizing this filler in the presence of glass-forming agents. Specifically, this study
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