Merck
CN
  • Dynamic scale theory for characterizing surface morphology of layer-by-layer films of poly(o-methoxyaniline).

Dynamic scale theory for characterizing surface morphology of layer-by-layer films of poly(o-methoxyaniline).

Journal of nanoscience and nanotechnology (2004-10-27)
Nara C de Souza, Josmary R Silva, Marcelo A Pereira-da-Silva, Maria Raposo, Roberto M Faria, José A Giacometti, Osvaldo N Oliveira
ABSTRACT

The dynamic scale theory and fractal concepts are employed in the characterization of surface morphological properties of layer-by-layer (LBL) films from poly(o-methoxyaniline) (POMA) alternated with poly(vinyl sulfonic acid) (PVS). The fractal dimensions are found to depend on the procedures to fabricate the POMA/PVS multilayers, particularly with regard to the drying procedures. LBL films obtained via drying in ambient air show a more homogeneous surface, compared to films dried under vacuum or a flow of nitrogen, due to a uniform rearrangement of polymer molecules during solvent evaporation.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
o-Anisidine, ≥99%
Sigma-Aldrich
Poly(vinylsulfonic acid, sodium salt) solution, 30-40 wt. % in H2O, technical grade