Merck
CN

Personal exposure to volatile organic compounds in the Czech Republic.

Journal of exposure science & environmental epidemiology (2012-06-07)
Vlasta Svecova, Jan Topinka, Ivo Solansky, Radim J Sram
ABSTRACT

Personal exposures to volatile organic compounds (VOCs) were measured in the three industrial cities in the Czech Republic, Ostrava, Karvina and Havirov, while the city of Prague served as a control in a large-scale molecular epidemiological study identifying the impacts of air pollution on human health. Office workers from Ostrava and city policemen from Karvina, Havirov and Prague were monitored in the winter and summer of 2009. Only adult non-smokers participated in the study (N=160). Radiello-diffusive passive samplers were used to measure the exposure to benzene, toluene, ethylbenzene, meta- plus para-xylene and ortho-xylene (BTEX). All participants completed a personal questionnaire and a time-location-activity diary (TLAD). The average personal BTEX exposure levels in both seasons were 7.2/34.3/4.4/16.1 μg/m(3), respectively. The benzene levels were highest in winter in Karvina, Ostrava and Prague: 8.5, 7.2 and 5.3 μg/m(3), respectively. The personal exposures to BTEX were higher than the corresponding stationary monitoring levels detected in the individual localities (P<0.001; except m,p-xylene in summer). The indoor environment, ETS (environmental tobacco smoke), cooking, a home-heating fireplace or gas stove, automobile use and being in a restaurant were important predictors for benzene personal exposure. Ostrava's outdoor benzene pollution was a significant factor increasing the exposure of the Ostrava study participants in winter (P<0.05).

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Xylenes, histological grade
radiello BTEX/VOC Starter Kit, CS2 Desorption
radiello Empty Storage Tubes, polypropylene (with stopper), volume 12 mL, pk of 100
radiello Diffusive Bodies, yellow, configured for reduced sampling rates, pk of 20
radiello Filtration Kit, pk of 20
radiello Diffusive Bodies, permeative, configured for anaesthetic gases and vapors, pk of 20
Sigma-Aldrich
Ethylbenzene solution, NMR reference standard, 1% in chloroform-d (99.8 atom % D)
radiello BTEX/VOC Starter Kit, Thermal Desorption
Supelco
radiello Methylene Blue Calibration Standard for H2S (Hydrogen Sulfide), pkg of 100 mL
radiello Empty Storage Tubes, glass (with stopper), volume 2.8 mL, pk of 100
radiello Clips, suspending Radiello triangular support plate, pk of 20
radiello On-Field Thermometer, Includes one standard Radiello vertical adapter (RAD122) for each thermometer, configured for standard use, pk of 3
radiello Diffusive Bodies, white, configured for general use, pk of 20
Supelco
radiello Aldehyde Calibration Standard, 50 μg/mL each component in acetonitrile, pkg of 10 mL
Supelco
Ethylbenzene solution, NMR reference standard, 10% in chloroform-d (99.8 atom % D), NMR tube size 5 mm × 8 in. , ultra-thin wall
Sigma-Aldrich
Ethylbenzene solution, NMR reference standard, 10% in chloroform-d (99.8 atom % D), NMR tube size 10 mm × 8 in.
Sigma-Aldrich
Ethylbenzene solution, NMR reference standard, 0.1% in chloroform-d ("100%", 99.96 atom % D)
Sigma-Aldrich
Ethylbenzene solution, NMR reference standard, 10% in chloroform-d (99.8 atom % D)
Sigma-Aldrich
Ethylbenzene solution, NMR reference standard, 0.1% in chloroform-d (99.8 atom % D), TMS 0.1 %
Sigma-Aldrich
Ethylbenzene solution, NMR reference standard, 5% in chloroform-d (99.8 atom % D), TMS 1 %, NMR tube size 5 mm × 7 in.
radiello 1,3-Butadiene Starter Kit, Thermal Desorption, pkg of 1 kit (2 RAD141 adsorbing cartridges and barcode labels, 1 RAD1202 yellow diffusive body, 1 RAD121 triangular support plate, 1 instruction sheet)
Supelco
radiello BTEX Calibration Kit (Thermal Desorption)
radiello On-Field Thermometer, Reader, pk of 1
radiello Diffusive Bodies, blue, configured for sampling light sensitive compounds, pk of 20
Supelco
radiello BTEX Calibration Kit (CS2 Desorption)
Supelco
m-Xylene, Pharmaceutical Secondary Standard; Certified Reference Material
Supelco
p-Xylene, Pharmaceutical Secondary Standard; Certified Reference Material
radiello Hydrogen Sulfide Starter Kit
Sigma-Aldrich
m-Xylene, puriss. p.a., ≥99.0% (GC)
Sigma-Aldrich
Xylenes, ACS reagent, ≥98.5% xylenes + ethylbenzene basis