- High catalytic activity of silicalite in gas-phase ketonisation of propionic acid.
High catalytic activity of silicalite in gas-phase ketonisation of propionic acid.
Chemical communications (Cambridge, England) (2013-03-19)
Hossein Bayahia, Elena Kozhevnikova, Ivan Kozhevnikov
PMID23503647
ABSTRACT
Amorphous silica and crystalline silicalite (MFI structure) are demonstrated to be active and environmentally benign catalysts for propionic acid ketonisation at 450-500 °C to form 3-pentanone. The silicalite is particularly efficient, and its ketonisation selectivity is increased by base modification probably through generation of silanol nests.
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