Skip to Content
Merck
CN
  • Syntheses of α-stannylated and α-iodinated enamides via molybdenum-catalyzed hydrostannation.

Syntheses of α-stannylated and α-iodinated enamides via molybdenum-catalyzed hydrostannation.

Organic letters (2013-11-12)
Pulakesh Maity, Manuel R Klos, Uli Kazmaier
PMID24206085
ABSTRACT

α-Stannylated and α-iodinated enamides can easily be obtained by molybdenum-catalyzed regio- and stereoselective hydrostannation and subsequent tin-iodine exchange. These functionalized enamides are interesting building blocks for a wide range of cross-coupling reactions giving access to various types of α-substituted enamides.

MATERIALS
Product Number
Brand
Product Description
366986
Sigma-Aldrich
Molybdenum, powder, 10 μm, ≥99.95% trace metals basis
577987
Sigma-Aldrich
Molybdenum, nanopowder, <100 nm particle size (TEM), 99.8% trace metals basis
510092
Sigma-Aldrich
Molybdenum, powder, 1-5 μm, ≥99.9% trace metals basis
266922
Sigma-Aldrich
Molybdenum, foil, thickness 0.1 mm, ≥99.9% trace metals basis
357227
Sigma-Aldrich
Molybdenum, foil, thickness 0.025 mm, ≥99.9% trace metals basis
266892
Sigma-Aldrich
Molybdenum, powder, <150 μm, 99.9% trace metals basis
357200
Sigma-Aldrich
Molybdenum, foil, thickness 1.0 mm, ≥99.9% trace metals basis
203823
Sigma-Aldrich
Molybdenum, powder, <150 μm, 99.99% trace metals basis
266914
Sigma-Aldrich
Molybdenum, wire, diam. 1.0 mm, 99.95% trace metals basis