Recent advances in homogeneous nickel catalysis.

Recent advances in homogeneous nickel catalysis.

Nature (2014-05-16)

Sarah Z Tasker, Eric A Standley, Timothy F Jamison

ABSTRACT

Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions. In recent years, these properties have been increasingly understood and used to perform transformations long considered exceptionally challenging. Here we discuss some of the most recent and significant developments in homogeneous nickel catalysis, with an emphasis on both synthetic outcome and mechanism.

MATERIALS

Product Number

Brand

Product Description

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

GF63510308

Nickel, foil, 10mm disks, thickness 0.125mm, as rolled, 100%

GF71201168

Nickel, sphere, 100pcs, diameter 0.76mm, precision sphere grade 200, 99%

GF85580983

Nickel, tube, 100mm, outside diameter 2.5mm, inside diameter 2.25mm, wall thickness 0.125mm, hard, 99.5%

GF15634054

Nickel, rod, 500mm, diameter 9.5mm, 99%

GF03591110

Nickel, foil, 1m coil, thickness 0.038mm, 99.9%

GF86286404

Nickel, foil, 15mm disks, thickness 0.05mm, as rolled, 100%

GF72676121

Nickel, tube, 200mm, outside diameter 1.8mm, inside diameter 1.6mm, wall thickness 0.1mm, hard, 99.5%

GF68841535

Nickel, foil, 10mm disks, thickness 0.20mm, annealed, 99%

901166

Sigma-Aldrich

cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride

GF12712418

Nickel, foil, 1m coil, thickness 1.0mm, annealed, 99.98%

GF54839188

Nickel, tube, 100mm, outside diameter 2.5mm, inside diameter 2mm, wall thickness 0.25mm, hard, 99.5%

GF43735800

Nickel, tube, 100mm, outside diameter 0.35mm, inside diameter 0.3mm, wall thickness 0.025mm, hard, 99.5%

900941

Sigma-Aldrich

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II), ≥95%

900944

Sigma-Aldrich

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II), ≥95%

GF83400364

Nickel, foil, not light tested, 100x100mm, thickness 0.002mm, 99.95%

GF89307063

Nickel, foil, not light tested, 25x25mm, thickness 0.001mm, 99.95%

GF08093796

Nickel, tube, 500mm, outside diameter 0.8mm, inside diameter 0.5mm, wall thickness 0.15mm, as drawn, 99.5%

GF45656691

Nickel, tube, 200mm, outside diameter 3.0mm, inside diameter 2.4mm, wall thickness 0.3mm, hard, 99.5%

GF72118403

Nickel, tube, 200mm, outside diameter 0.75mm, inside diameter 0.59mm, wall thickness 0.08mm, hard, 99.5%

GF56645499

Nickel, foil, 25mm disks, thickness 0.003mm, 99.95%

GF38428241

Nickel, foil, 25mm disks, thickness 0.025mm, annealed, 99%

GF69689862

Nickel, wire reel, 200m, diameter 0.25mm, hard, 99.98%

GF64803393

Nickel, tube, 35mm, outside diameter 7.8mm, inside diameter 6.4mm, wall thickness 0.7mm, hard, 99.5%

GF07573989

Nickel, wire reel, 5m, diameter 2.0mm, hard, 99.98%

GF73660530

Nickel, tube, 200mm, outside diameter 1.5mm, inside diameter 1.2mm, wall thickness 0.15mm, hard, 99.5%