900944
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II)
≥95%, powder or solid
Synonym(s):
SK-J002-1n
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Empirical Formula (Hill Notation):
C39H44ClFeNNiP2
CAS Number:
Molecular Weight:
738.71
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
Product Name
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II), ≥95%
Quality Segment
assay
≥95%
form
powder or solid
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
reaction type: Asymmetric synthesis
SMILES string
CC(C)(C)P(C(C)(C)C)C[C]1[C][C][C][C]1P(C2=CC=CC=C2)C3=CC=CC=C3.[Ni+2]C4=CC=C(C#N)C=C4.[C]5[C][C][C][C]5.[Fe]
Application
Amination of aryl chlorides with ammonia.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Evaluating 1, 1?-Bis (phosphino) ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C?N Cross-Coupling of (Hetero) aryl Chlorides.
Clark J S, et al.
Organometallics, 36(3), 679-686 (2017)
Nickel?Catalyzed Monoarylation of Ammonia.
Borzenko A, et al.
Angewandte Chemie (International Edition in English), 54(12), 3773-3777 (2015)
Ni?Catalyzed Amination Reactions: An Overview.
Marin M, et al.
Chemical Record, 16(4), 1819-1832 (2016)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 900944-250MG | 04061833315316 |