- meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone.
meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone.
Organic & biomolecular chemistry (2015-05-30)
Mikhail A Filatov, Ernesta Heinrich, Katharina Landfester, Stanislav Baluschev
PMID26023033
ABSTRACT
Fusion with a 9,10-anthraquinone moiety was achieved to extend porphyrin's π-system. A bridged dihydroisoindole derivative was used to prepare the corresponding meso-tetraphenyltetraanthraquinonoporphyrin (Ph4TAQP) via a thermal retro-Diels-Alder reaction. The basic optical properties of the prepared new anthraquinonoporphyrin and its complexes with Zn and Pd were studied.
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