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Merck
CN

249742

十二羰基三锇

98%

别名:

三锇十二羰基, 羰基锇

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关于此项目

线性分子式:
Os3(CO)12
化学文摘社编号:
分子量:
906.81
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
239-789-3
MDL number:
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产品名称

十二羰基三锇, 98%

InChI key

VUBLMKVEIPBYME-UHFFFAOYSA-N

InChI

1S/12CO.3Os/c12*1-2;;;

SMILES string

[Os].[Os].[Os].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

assay

98%

form

powder or crystals

reaction suitability

core: osmium
reagent type: catalyst

mp

224 °C (lit.)

Quality Level

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Application

氧化物配合物与 1-羟基吡啶-2-硫酮的起始原料。合成 [Os(CO)4(SnPh2)]6 的关键原料,这种化合物具有前所未有的 12 元金属原子环。

Features and Benefits

  • High Purity and Crystallinity: Typically offered with >98% purity.
  • Photochemically Active: Under UV or visible light, it releases CO ligands to form reactive intermediates such as Os₃(CO)₁₁
  • Solubility in Organic Solvents: Soluble in chlorinated solvents, ethers, and aromatic hydrocarbons.

General description

Triosmium dodecacarbonyl is a high-purity (98%) organometallic compound available in powder or crystalline form, widely used as a precursor in solution and vapor deposition techniques. It features three osmium atoms bridged by twelve carbonyl ligands, offering excellent volatility and thermal stability for thin films and nanomaterials. It is primarily used in the development of energy materials, inorganic catalysts, and in chemical vapor deposition (CVD) and atomic layer deposition (ALD) processes. These applications make it especially valuable in catalysis research and semiconductor manufacturing.

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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Hung, J-T. et al.
Organometallics, 15, 5605-5605 (1996)
Leong, W.K. et al.
Organometallics, 16, 1079-1079 (1997)

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