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Merck
CN

259160

1,4,8,11-四氮杂环十四烷

98% (GC)

别名:

1,4,8,11-四氮环十四烷

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关于此项目

经验公式（希尔记法）:
C10H24N4
化学文摘社编号:
295-37-4
分子量:
200.32
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
24855689
EC Number:
206-039-1
Beilstein/REAXYS Number:
111811
MDL number:
MFCD00005105

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产品名称

1,4,8,11-四氮杂环十四烷, 98% (GC)

InChI key

MDAXKAUIABOHTD-UHFFFAOYSA-N

InChI

1S/C10H24N4/c1-3-11-7-9-13-5-2-6-14-10-8-12-4-1/h11-14H,1-10H2

SMILES string

C1CNCCNCCCNCCNC1

assay

98% (GC)

mp

184-186 °C (lit.)

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相关类别

Application

1,4,8,11-四氮杂环十四烷(cyclam)可作为配体用于合成：
  • 氰化物桥联FeIII-CuII配合物。
  • 具有抗菌性的芬那酸锌配合物[Zn(cyclam)(fen)2]，fen=芬那酸。
  • Zn(II)氟芬那酸
  • (flu)配合物，[Zn(cyclam)(flu)2]。
  • 多金属氧酸盐-有机金属框架，如[{Cu(cyclam)}3(W7O24)].15.5.H2O。

General description

1,4,8,11-四氮杂环十四烷是一种氮杂大环，可形成比开链配体更稳定的金属配合物。

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCX6563
MKCX1975
MKCX0407
MKCX0406
MKCX0405

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Jing Li et al.
Biomacromolecules, 13(10), 3220-3227 (2012-09-26)
A series of reducible polycationic copper chelators (RPCs) based on 1,4,8,11-tetraazacyclotetradecane (cyclam) were synthesized by Michael addition. Molecular weight of the polycations was controlled by reaction stoichiometry and reaction conditions, resulting in polymers with molecular weights ranging from 4400 to
Abir El Majzoub et al.
Inorganic chemistry, 50(9), 4029-4038 (2011-04-12)
The coordination properties and the photophysical response of a new cyclam fluorescent probe for Zn(II), [L1H: 1-(benzimidazol-2-ylmethyl]-1,4, 8,11-tetraazacyclotetradecane] toward Cu(II), Zn(II), and Cd(II) are reported. The stability constants of the corresponding complexes were determined by means of potentiometric measurements in
Cyclam (1,4,8,11-tetraazacyclotetradecane) with one methylphosphonate pendant arm: a new ligand for selective copper (II) binding.
F?zerova S, et al.
Dalton Transactions, 2908-2915 (2005)
Mingfeng Yu et al.
Inorganic chemistry, 50(24), 12823-12835 (2011-11-25)
We describe the synthesis of cyclam metal complexes derivatized with amino acids or a tripeptide using a copper(I)-catalyzed Huisgen "click" reaction. The linker triazole formed during the synthesis plays an active coordinating role in the complexes. The reaction conditions do
Michael Schmittel et al.
Chemical communications (Cambridge, England), 48(96), 11730-11732 (2012-10-20)
The two states of a new nanomechanical switch were quantitatively and reversibly populated in several subsequent switching cycles using either Cu(+) or cyclam as chemical inputs. State II was demonstrated to cis-trans isomerise diazastilbene upon irradiation selectively in the presence
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