Merck
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文件

259160

Sigma-Aldrich

1,4,8,11-四氮杂环十四烷

98% (GC)

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别名:
1,4,8,11-四氮环十四烷
经验公式（希尔记法）:
C10H24N4
CAS号:
295-37-4
分子量:
200.32
Beilstein:
111811
EC 号:
206-039-1
MDL编号:
MFCD00005105
PubChem化学物质编号:
24855689
NACRES:
NA.22

检测方案

98% (GC)

mp

184-186 °C (lit.)

SMILES string

C1CNCCNCCCNCCNC1

InChI

1S/C10H24N4/c1-3-11-7-9-13-5-2-6-14-10-8-12-4-1/h11-14H,1-10H2

InChI key

MDAXKAUIABOHTD-UHFFFAOYSA-N

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相关类别

一般描述

1,4,8,11-四氮杂环十四烷是一种氮杂大环，可形成比开链配体更稳定的金属配合物。

应用

1,4,8,11-四氮杂环十四烷(cyclam)可作为配体用于合成：
  • 氰化物桥联FeIII-CuII配合物。
  • 具有抗菌性的芬那酸锌配合物[Zn(cyclam)(fen)2]，fen=芬那酸。
  • Zn(II)氟芬那酸
  • (flu)配合物，[Zn(cyclam)(flu)2]。
  • 多金属氧酸盐-有机金属框架，如[{Cu(cyclam)}3(W7O24)].15.5.H2O。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315 - H319

危险分类

Eye Irrit. 2 - Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Abir El Majzoub et al.
Inorganic chemistry, 50(9), 4029-4038 (2011-04-12)
The coordination properties and the photophysical response of a new cyclam fluorescent probe for Zn(II), [L1H: 1-(benzimidazol-2-ylmethyl]-1,4, 8,11-tetraazacyclotetradecane] toward Cu(II), Zn(II), and Cd(II) are reported. The stability constants of the corresponding complexes were determined by means of potentiometric measurements in
Cyclam (1,4,8,11-tetraazacyclotetradecane) with one methylphosphonate pendant arm: a new ligand for selective copper (II) binding.
F?zerova S, et al.
Dalton Transactions, 2908-2915 (2005)
Apurba Kalita et al.
Inorganic chemistry, 50(23), 11868-11876 (2011-11-02)
The nitric oxide reactivity of two copper(II) complexes, 1 and 2 with ligands L(1) and L(2), respectively, [L(1) = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, L(2) = 5,5,7-trimethyl-[1,4]-diazepane] have been studied. The copper(II) center in complex 1 was found to be unreactive toward nitric oxide
Jing Li et al.
Biomacromolecules, 13(10), 3220-3227 (2012-09-26)
A series of reducible polycationic copper chelators (RPCs) based on 1,4,8,11-tetraazacyclotetradecane (cyclam) were synthesized by Michael addition. Molecular weight of the polycations was controlled by reaction stoichiometry and reaction conditions, resulting in polymers with molecular weights ranging from 4400 to
Mingfeng Yu et al.
Inorganic chemistry, 50(24), 12823-12835 (2011-11-25)
We describe the synthesis of cyclam metal complexes derivatized with amino acids or a tripeptide using a copper(I)-catalyzed Huisgen "click" reaction. The linker triazole formed during the synthesis plays an active coordinating role in the complexes. The reaction conditions do
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