302473
双环辛烯氯化铑二聚体
98%, powder
别名:
[Rh(coe)2Cl]2
登录 查看组织和合同定价。
选择尺寸
变更视图
关于此项目
经验公式（希尔记法）:
C32H56Cl2Rh2
化学文摘社编号:
分子量:
717.50
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
双环辛烯氯化铑二聚体, 98%
Quality Level
assay
98%
form
powder
reaction suitability
core: rhodium, reagent type: catalyst
mp
190 °C (dec.) (lit.)
SMILES string
Cl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4
InChI
1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChI key
GQPAPAIPOLEZHT-XFCUKONHSA-L
Application
双环辛烯氯化铑(I)二聚体可用作以下反应的催化剂：
- 通过芳基硼酸与α,β-不饱和磺酰基化合物的不对称1,4-加成，合成富对映体的偕二芳基磺酸盐。
- N脱保护吲哚和吡咯的直接C-芳基化。
- 通过C-H键活化的在芳烃羧化反应。
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
商品
Discover the role of boronic acids in enantioenriched C(sp2)–C(sp2) product synthesis, specifically the rhodium-catalyzed Suzuki–Miyaura-type arylations of allylic halides and cyclobutenes.
Rhodium-catalyzed C-C bond cleavage reactions-an update
Korotvicka A, et al.
Current Organic Chemistry, 16(10), 1170-1214 (2012)
Substrate control of stereoselection in the rhodium (I) catalyzed intramolecular [4+ 2] cycloaddition reaction
O'Mahony DJR, et al.
Organic & Biomolecular Chemistry, 1(12), 2038-2040 (2003)
Chiral Phosphite-Olefin Ligands: Application in Rh-Catalyzed Asymmetric 1, 4-Addition of Arylboronic Acids to beta-Aryl-alpha, beta-unsaturated Sulfonates
Yue-Na Y and Ming-Hua X
Acta Chimica Sinica , 72(7), 815-819 (2014)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 302473-1G | 04061826665893 |
| 302473-250MG | 04061833546390 |