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Merck
CN

302473

双环辛烯氯化铑二聚体

98%, powder

别名:

[Rh(coe)2Cl]2

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关于此项目

经验公式（希尔记法）:
C32H56Cl2Rh2
化学文摘社编号:
12279-09-3
分子量:
717.50
UNSPSC Code:
12161600
PubChem Substance ID:
24858255
NACRES:
NA.22
MDL number:
MFCD00013287

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产品名称

双环辛烯氯化铑二聚体, 98%

SMILES string

Cl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4

InChI

1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;

InChI key

GQPAPAIPOLEZHT-XFCUKONHSA-L

assay

98%

form

powder

reaction suitability

core: rhodium
reagent type: catalyst

mp

190 °C (dec.) (lit.)

Quality Level

100

相关类别

Application

双环辛烯氯化铑(I)二聚体可用作以下反应的催化剂：
  • 通过芳基硼酸与α,β-不饱和磺酰基化合物的不对称1,4-加成，合成富对映体的偕二芳基磺酸盐。
  • N脱保护吲哚和吡咯的直接C-芳基化。
  • 通过C-H键活化的在芳烃羧化反应。

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ0929
MKCV3539
MKCR7327
MKCQ3486
MKCP8266

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Rhodium (I)-catalyzed direct carboxylation of arenes with CO2 via chelation-assisted C- H bond activation
Mizuno H, et al.
Journal of the American Chemical Society, 133(5), 1251-1253 (2011)
Jay A Labinger et al.
Nature, 417(6888), 507-514 (2002-05-31)
The selective transformation of ubiquitous but inert C H bonds to other functional groups has far-reaching practical implications, ranging from more efficient strategies for fine chemical synthesis to the replacement of current petrochemical feedstocks by less expensive and more readily
Fumitoshi Kakiuchi et al.
Accounts of chemical research, 35(10), 826-834 (2002-10-16)
The cleavage and addition of ortho C-H bonds in various aromatic compounds such as ketones, esters, imines, imidates, nitrile, and aldehydes to olefins and acetlylenes can be achieved catalytically with the aid of ruthenium catalysts. The reaction is generally highly
Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions.
K L Tan et al.
Journal of the American Chemical Society, 123(11), 2685-2686 (2001-07-18)
Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H activation and addition on unsaturated substrates: reactions and mechanistic aspects.
Vincent Ritleng et al.
Chemical reviews, 102(5), 1731-1770 (2002-05-09)
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